Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide
| ISSN: |
1572-8927
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|---|---|
| Keywords: |
Electrolytic conductance ; alkali metal iodides and thiocyanates ; TINO3 ; NH4SCN ; hexamethylphosphotriamide ; ionic association
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798296411225194496 |
|---|---|
| autor | Hanna, E. M. Al-Salihi, N. J. |
| autorsonst | Hanna, E. M. Al-Salihi, N. J. |
| book_url | http://dx.doi.org/10.1007/BF00655210 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM197890717 |
| issn | 1572-8927 |
| journal_name | Journal of solution chemistry |
| materialart | 1 |
| notes | Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated. |
| package_name | Springer |
| publikationsjahr_anzeige | 1979 |
| publikationsjahr_facette | 1979 |
| publikationsjahr_intervall | 8024:1975-1979 |
| publikationsjahr_sort | 1979 |
| publisher | Springer |
| reference | 8 (1979), S. 539-547 |
| schlagwort | Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association |
| search_space | articles |
| shingle_author_1 | Hanna, E. M. Al-Salihi, N. J. |
| shingle_author_2 | Hanna, E. M. Al-Salihi, N. J. |
| shingle_author_3 | Hanna, E. M. Al-Salihi, N. J. |
| shingle_author_4 | Hanna, E. M. Al-Salihi, N. J. |
| shingle_catch_all_1 | Hanna, E. M. Al-Salihi, N. J. Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated. 1572-8927 15728927 Springer |
| shingle_catch_all_2 | Hanna, E. M. Al-Salihi, N. J. Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated. 1572-8927 15728927 Springer |
| shingle_catch_all_3 | Hanna, E. M. Al-Salihi, N. J. Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated. 1572-8927 15728927 Springer |
| shingle_catch_all_4 | Hanna, E. M. Al-Salihi, N. J. Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Electrolytic conductance alkali metal iodides and thiocyanates TINO3 NH4SCN hexamethylphosphotriamide ionic association Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated. 1572-8927 15728927 Springer |
| shingle_title_1 | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| shingle_title_2 | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| shingle_title_3 | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| shingle_title_4 | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Springer Online Journal Archives 1860-2000 |
| timestamp | 2024-05-06T09:51:39.495Z |
| titel | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| titel_suche | Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide |
| topic | V |
| uid | nat_lic_papers_NLM197890717 |