Conductance and solvation of uni-univalent electrolytes in hexamethylphosphotriamide
| ISSN: |
1572-8927
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| Keywords: |
Electrolytic conductance ; alkali metal iodides and thiocyanates ; TINO3 ; NH4SCN ; hexamethylphosphotriamide ; ionic association
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract The conductances of KI, RbI, CsI, TINO3 NaSCN, KSCN, and NH4SCN have been measured in hexamethylphosphotriamide at 25°C in the concentration range up to 9.5×10−3 M. The data have been analyzed with the expanded and full versions of the Pitts and Fuoss-Hsia conductance equations. With the exception of thallium(I) nitrate the association constants of all the salts studied are small. Computed values of the limiting molar conductanceA o and the association constantsK A indicate that metal cations are strongly solvated while anions are at best weakly solvated.
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| Type of Medium: |
Electronic Resource
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| URL: |