Geometric effects of deuteration on hydrogen-ordering phase transitions
McMahon, M. I. ; Nelmes, R. J. ; Kuhst, W. F. ; Dorwarth, R. ; Piltz, R. O. ; Tun, Z.
[s.l.] : Nature Publishing Group
Published 1990
[s.l.] : Nature Publishing Group
Published 1990
ISSN: |
1476-4687
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Source: |
Nature Archives 1869 - 2009
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Topics: |
Biology
Chemistry and Pharmacology
Medicine
Natural Sciences in General
Physics
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Notes: |
[Auszug] KH2PO4 (KDP) undergoes an H-ordering phase transition to a ferroelectric phase on cooling through Tc= 122 K at atmospheric pressure. Above Tc, the H atoms are 50:50 disordered over two sites, 8 apart, in short O-H-O bonds of length 2R linking the PO4 tetrahedra. Below Tc, the H atoms order fully ...
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Type of Medium: |
Electronic Resource
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URL: |