An experimental investigation of the nf Rydberg states of carbon disulfide
| ISSN: |
1089-7690
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|---|---|
| Source: |
AIP Digital Archive
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| Topics: |
Physics
Chemistry and Pharmacology
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| Notes: |
The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798289774312685569 |
|---|---|
| autor | Berger, J.-P. Couris, S. |
| autorsonst | Berger, J.-P. Couris, S. |
| book_url | http://dx.doi.org/10.1063/1.475178 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLZ219089922 |
| issn | 1089-7690 |
| journal_name | The Journal of Chemical Physics |
| materialart | 1 |
| notes | The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics. |
| package_name | American Institute of Physics (AIP) |
| publikationsjahr_anzeige | 1997 |
| publikationsjahr_facette | 1997 |
| publikationsjahr_intervall | 8004:1995-1999 |
| publikationsjahr_sort | 1997 |
| publikationsort | College Park, Md. |
| publisher | American Institute of Physics (AIP) |
| reference | 107 (1997), S. 8866-8873 |
| search_space | articles |
| shingle_author_1 | Berger, J.-P. Couris, S. |
| shingle_author_2 | Berger, J.-P. Couris, S. |
| shingle_author_3 | Berger, J.-P. Couris, S. |
| shingle_author_4 | Berger, J.-P. Couris, S. |
| shingle_catch_all_1 | Berger, J.-P. Couris, S. An experimental investigation of the nf Rydberg states of carbon disulfide The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics. 1089-7690 10897690 American Institute of Physics (AIP) |
| shingle_catch_all_2 | Berger, J.-P. Couris, S. An experimental investigation of the nf Rydberg states of carbon disulfide The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics. 1089-7690 10897690 American Institute of Physics (AIP) |
| shingle_catch_all_3 | Berger, J.-P. Couris, S. An experimental investigation of the nf Rydberg states of carbon disulfide The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics. 1089-7690 10897690 American Institute of Physics (AIP) |
| shingle_catch_all_4 | Berger, J.-P. Couris, S. An experimental investigation of the nf Rydberg states of carbon disulfide The (2Πg3/2,1/2)nf Rydberg states of CS2 are investigated by means of (3+1) resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) spectroscopy. The excitation spectrum of jet-cooled carbon disulfide has been obtained in the 74 000–81 000 cm−1 energy region. From the CS2+ mass selected REMPI spectra, the nf Rydberg series have been clearly identified and they have been found converging to the two spin–orbit components of the CS2+ (X 2Πg) ground state corresponding to the n=4–11 members. Comparison of the CS2+, CS+, S+ mass selected REMPI spectra gave a better insight of the competition between dissociation and ionization processes. The use of linearly and circularly polarized laser light, selection rules and quantum defect considerations have led to a preliminary analysis of the measured nf complexes. © 1997 American Institute of Physics. 1089-7690 10897690 American Institute of Physics (AIP) |
| shingle_title_1 | An experimental investigation of the nf Rydberg states of carbon disulfide |
| shingle_title_2 | An experimental investigation of the nf Rydberg states of carbon disulfide |
| shingle_title_3 | An experimental investigation of the nf Rydberg states of carbon disulfide |
| shingle_title_4 | An experimental investigation of the nf Rydberg states of carbon disulfide |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | AIP Digital Archive |
| timestamp | 2024-05-06T08:06:11.047Z |
| titel | An experimental investigation of the nf Rydberg states of carbon disulfide |
| titel_suche | An experimental investigation of the nf Rydberg states of carbon disulfide |
| topic | U V |
| uid | nat_lic_papers_NLZ219089922 |