Effect of an electric field on a methane molecule. I. Infrared analysis of methane (CH4–CD4) adsorbed in NaA zeolite in the temperature range 150–20 K
De Lara, E. Cohen ; Kahn, R. ; Seloudoux, R.
College Park, Md. : American Institute of Physics (AIP)
Published 1985
College Park, Md. : American Institute of Physics (AIP)
Published 1985
| ISSN: |
1089-7690
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| Source: |
AIP Digital Archive
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| Topics: |
Physics
Chemistry and Pharmacology
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| Notes: |
The spectra of methane adsorbed at low temperature in NaA zeolite show two strong effects of the field existing in the cavities: (i) the appearance of the ν1 forbidden band which increases when decreasing the temperature and (ii) the splitting of the ν3 degenerate band. The variation with T of its components lead to the conclusion that the molecule progressively is oriented in a C3V configuration with respect to the field.
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| Type of Medium: |
Electronic Resource
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| URL: |