Experimental ESR method for investigating slow-orientational diffusion of normal nitroxides with 14N(I=1)
| ISSN: |
1089-7690
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| Source: |
AIP Digital Archive
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| Topics: |
Physics
Chemistry and Pharmacology
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| Notes: |
The general theoretical-experimental method recently formulated for investigating dynamic properties of slow-orientational anisotropic ESR hyperfine centers under orientational diffusion is applied to normal nitroxide radicals with14N(I=1). This application permits the determination of slow-orientational correlation times, motional inhomogeneous linewidths, and temperature-dependent hyperfine coupling constants from the first- and second-derivative peak positions of nitroxide ESR hyperfine structures in polycrystalline-amorphous condensed matter.
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| Type of Medium: |
Electronic Resource
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| URL: |