A study of the structure and dynamics of the hydronium ion by high resolution infrared laser spectroscopy. III. The ν3 band of D3O+
Petek, H. ; Nesbitt, D. J. ; Owrutsky, J. C. ; Gudeman, C. S. ; Yang, X. ; Harris, D. O. ; Moore, C. B. ; Saykally, R. J.
College Park, Md. : American Institute of Physics (AIP)
Published 1990
College Park, Md. : American Institute of Physics (AIP)
Published 1990
| ISSN: |
1089-7690
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| Source: |
AIP Digital Archive
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| Topics: |
Physics
Chemistry and Pharmacology
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| Notes: |
294 transitions were measured by velocity modulation spectroscopy using a difference frequency laser system with a D2/O2 discharge and assigned to the ν3 (antisymmetric stretch) band of D3O+. A simultaneous analysis of this data with the ν2 band spectra reported by Sears, et al. [J. Chem. Phys. 83, 2676 (1985)] yielded a refined set of parameters for both the ground and the excited states of both bands. The ν3 bandcenters are 2629.6512(39) and 2624.2376(47) cm−1 for the s–s and a–a inversion components, respectively.
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| Type of Medium: |
Electronic Resource
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| URL: |