The x-ray excited Auger electron spectrum of NO and potential curves and photodissociation of the NO2+ ion
Pettersson, L. G. M. ; Karlsson, L. ; Keane, M. P. ; Naves de Brito, A. ; Correia, N. ; Larsson, M. ; Broström, L. ; Mannervik, S. ; Svensson, S.
College Park, Md. : American Institute of Physics (AIP)
Published 1992
College Park, Md. : American Institute of Physics (AIP)
Published 1992
| ISSN: |
1089-7690
|
|---|---|
| Source: |
AIP Digital Archive
|
| Topics: |
Physics
Chemistry and Pharmacology
|
| Notes: |
A study of the NO2+ ion by means of Auger spectroscopy, fast ion beam laser spectroscopy and ab initio calculations is reported. The photon induced Auger spectrum of NO was recorded. Potential curves for a number of electronic states of NO2+ were calculated by the complete active space SCF method in order to facilitate an analysis of the Auger spectrum. A photoabsorption spectrum of NO2+ was observed by means of photofragment kinetic energy spectroscopy and assigned to the A 2Π←X 2Σ+ transition. The two different experimental methods both give a value of 38.6 eV for the appearance energy of NO2+, which is entirely consistent with recent photoionization and double charge transfer results.
|
| Type of Medium: |
Electronic Resource
|
| URL: |