Optical band gap and Urbach tail in Y-doped BaCeO3

He, T. ; Ehrhart, P. ; Meuffels, P.

[S.l.] : American Institute of Physics (AIP)
Published 1996
ISSN:
1089-7550
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
_version_ 1798289647598567425
autor He, T.
Ehrhart, P.
Meuffels, P.
autorsonst He, T.
Ehrhart, P.
Meuffels, P.
book_url http://dx.doi.org/10.1063/1.361267
datenlieferant nat_lic_papers
hauptsatz hsatz_simple
identnr NLZ218515685
issn 1089-7550
journal_name Journal of Applied Physics
materialart 1
notes Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
package_name American Institute of Physics (AIP)
publikationsjahr_anzeige 1996
publikationsjahr_facette 1996
publikationsjahr_intervall 8004:1995-1999
publikationsjahr_sort 1996
publikationsort [S.l.]
publisher American Institute of Physics (AIP)
reference 79 (1996), S. 3219-3223
search_space articles
shingle_author_1 He, T.
Ehrhart, P.
Meuffels, P.
shingle_author_2 He, T.
Ehrhart, P.
Meuffels, P.
shingle_author_3 He, T.
Ehrhart, P.
Meuffels, P.
shingle_author_4 He, T.
Ehrhart, P.
Meuffels, P.
shingle_catch_all_1 He, T.
Ehrhart, P.
Meuffels, P.
Optical band gap and Urbach tail in Y-doped BaCeO3
Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_2 He, T.
Ehrhart, P.
Meuffels, P.
Optical band gap and Urbach tail in Y-doped BaCeO3
Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_3 He, T.
Ehrhart, P.
Meuffels, P.
Optical band gap and Urbach tail in Y-doped BaCeO3
Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_4 He, T.
Ehrhart, P.
Meuffels, P.
Optical band gap and Urbach tail in Y-doped BaCeO3
Optical processes at the absorption edge in Y-doped BaCeO3 films with thicknesses of 160 and 4600 nm have been studied in the temperature region between 20 and 1000 °C. For the first time, optical band-gap energies of Y-doped BaCeO3 were determined with a room temperature value of 4.1 eV and a temperature coefficient of −3.88×10−4 eV/K. It was found that the optical absorption coefficient below the band–band transition exhibits an exponential dependence on photon energy following Urbach's rule, and the Urbach tail is dependent on oxygen partial pressures, i.e., on lattice defects. The corresponding Urbach edge parameters and their temperature dependence were investigated. The data are discussed within the model of structural and thermal disorder and a characteristic phonon energy of 46 meV was obtained according to this disorder model. © 1996 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_title_1 Optical band gap and Urbach tail in Y-doped BaCeO3
shingle_title_2 Optical band gap and Urbach tail in Y-doped BaCeO3
shingle_title_3 Optical band gap and Urbach tail in Y-doped BaCeO3
shingle_title_4 Optical band gap and Urbach tail in Y-doped BaCeO3
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timestamp 2024-05-06T08:04:09.866Z
titel Optical band gap and Urbach tail in Y-doped BaCeO3
titel_suche Optical band gap and Urbach tail in Y-doped BaCeO3
topic U
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