Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces

Hopf, C. ; Schwarz-Selinger, T. ; Jacob, W. ; von Keudell, A.

[S.l.] : American Institute of Physics (AIP)
Published 2000
ISSN:
1089-7550
Source:
AIP Digital Archive
Topics:
Physics
Notes:
The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
_version_ 1798289688221450243
autor Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
autorsonst Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
book_url http://dx.doi.org/10.1063/1.372246
datenlieferant nat_lic_papers
hauptsatz hsatz_simple
identnr NLZ218405383
issn 1089-7550
journal_name Journal of Applied Physics
materialart 1
notes The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
package_name American Institute of Physics (AIP)
publikationsjahr_anzeige 2000
publikationsjahr_facette 2000
publikationsjahr_intervall 7999:2000-2004
publikationsjahr_sort 2000
publikationsort [S.l.]
publisher American Institute of Physics (AIP)
reference 87 (2000), S. 2719-2725
search_space articles
shingle_author_1 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
shingle_author_2 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
shingle_author_3 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
shingle_author_4 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
shingle_catch_all_1 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_2 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_3 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_catch_all_4 Hopf, C.
Schwarz-Selinger, T.
Jacob, W.
von Keudell, A.
Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
The surface loss probabilities of hydrocarbon radicals on the surface of amorphous hydrogenated carbon (C:H) films are investigated by depositing films inside a cavity with walls made from silicon substrates. This cavity is exposed to a discharge using different hydrocarbon source gases. Particles from the plasma can enter the cavity through a slit. The surface loss probability β is determined by analysis of the deposition profile inside the cavity. This surface loss probability corresponds to the sum of the probabilities of effective sticking on the surface and formation of a nonreactive volatile product via surface reactions. By comparing the deposition profiles measured in CH4, C2H2, C2H4, C2H6 discharges one obtains for C2H radicals β=0.80±0.05, for C2H3 radicals β=0.35±0.1, and for C2H5 radicals β〈10−3. The growth rate of C:H films is, therefore, very sensitive to any contribution of undersaturated C2Hx species in the impinging flux from a hydrocarbon discharge. © 2000 American Institute of Physics.
1089-7550
10897550
American Institute of Physics (AIP)
shingle_title_1 Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
shingle_title_2 Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
shingle_title_3 Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
shingle_title_4 Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
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source_archive AIP Digital Archive
timestamp 2024-05-06T08:04:48.816Z
titel Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
titel_suche Surface loss probabilities of hydrocarbon radicals on amorphous hydrogenated carbon film surfaces
topic U
uid nat_lic_papers_NLZ218405383