A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
Noheda, B. ; Cox, D. E. ; Shirane, G.
Woodbury, NY : American Institute of Physics (AIP)
Published 1999
Woodbury, NY : American Institute of Physics (AIP)
Published 1999
ISSN: |
1077-3118
|
---|---|
Source: |
AIP Digital Archive
|
Topics: |
Physics
|
Notes: |
A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics.
|
Type of Medium: |
Electronic Resource
|
URL: |
_version_ | 1798289608258093056 |
---|---|
autor | Noheda, B. Cox, D. E. Shirane, G. |
autorsonst | Noheda, B. Cox, D. E. Shirane, G. |
book_url | http://dx.doi.org/10.1063/1.123756 |
datenlieferant | nat_lic_papers |
hauptsatz | hsatz_simple |
identnr | NLZ218088612 |
issn | 1077-3118 |
journal_name | Applied Physics Letters |
materialart | 1 |
notes | A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics. |
package_name | American Institute of Physics (AIP) |
publikationsjahr_anzeige | 1999 |
publikationsjahr_facette | 1999 |
publikationsjahr_intervall | 8004:1995-1999 |
publikationsjahr_sort | 1999 |
publikationsort | Woodbury, NY |
publisher | American Institute of Physics (AIP) |
reference | 74 (1999), S. 2059-2061 |
search_space | articles |
shingle_author_1 | Noheda, B. Cox, D. E. Shirane, G. |
shingle_author_2 | Noheda, B. Cox, D. E. Shirane, G. |
shingle_author_3 | Noheda, B. Cox, D. E. Shirane, G. |
shingle_author_4 | Noheda, B. Cox, D. E. Shirane, G. |
shingle_catch_all_1 | Noheda, B. Cox, D. E. Shirane, G. A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics. 1077-3118 10773118 American Institute of Physics (AIP) |
shingle_catch_all_2 | Noheda, B. Cox, D. E. Shirane, G. A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics. 1077-3118 10773118 American Institute of Physics (AIP) |
shingle_catch_all_3 | Noheda, B. Cox, D. E. Shirane, G. A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics. 1077-3118 10773118 American Institute of Physics (AIP) |
shingle_catch_all_4 | Noheda, B. Cox, D. E. Shirane, G. A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov. © 1999 American Institute of Physics. 1077-3118 10773118 American Institute of Physics (AIP) |
shingle_title_1 | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
shingle_title_2 | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
shingle_title_3 | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
shingle_title_4 | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
sigel_instance_filter | dkfz geomar wilbert ipn albert |
source_archive | AIP Digital Archive |
timestamp | 2024-05-06T08:03:30.428Z |
titel | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
titel_suche | A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution |
topic | U |
uid | nat_lic_papers_NLZ218088612 |