Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing

Cho, W.-I. ; Yi, C.-W. ; Ju, J.-B. ; Cho, B.-W. ; Yun, K.-S.

Amsterdam : Elsevier
ISSN:
0925-4005
Source:
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
Topics:
Chemistry and Pharmacology
Electrical Engineering, Measurement and Control Technology
Type of Medium:
Electronic Resource
URL:
_version_ 1798292121212420096
autor Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
autorsonst Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
book_url http://linkinghub.elsevier.com/retrieve/pii/0925-4005(91)80236-D
datenlieferant nat_lic_papers
fussnote A solid electrolyte oxygen sensor has been prepared by the implementation of r.f. magnetron sputtering and electron-beam evaporation methods. Thin films of LaF"3 are applied as F^- ion-conducting solid electrolytes and a sensing electrode made of platinum black or an electron-beam evaporated Pt film is coated on the surface of the solid electrolytes. Co-sputtered Sn-SnF"2 films or electron-beam evaporated Sn/SnF"2 multilayered films are used as a reference electrode. The potential of the sensing electrode relative to that of the reference electrode changes logarithmically with the dissolved oxygen concentration in distilled water, but small e.m.f. changes are observed in a gas environment. The structure of LaF"3 is found to be microcrystalline when formed by electron-beam evaporation and the r.f. magnetron sputtering method. The capacitance of a thin-film type sensor has been examined with the aid of an impedance technique. When the sensor is exposed to oxygen, the capacitance value decreases because of the increase of F^- ion migration flux due to the adsorption of oxygen atoms on the sensing electrode surface.
hauptsatz hsatz_simple
identnr NLZ188483551
issn 0925-4005
journal_name Sensors and Actuators B: Chemical
materialart 1
package_name Elsevier
publikationsort Amsterdam
publisher Elsevier
reference 5 (1991), S. 149-153
search_space articles
shingle_author_1 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
shingle_author_2 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
shingle_author_3 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
shingle_author_4 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
shingle_catch_all_1 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
0925-4005
09254005
Elsevier
shingle_catch_all_2 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
0925-4005
09254005
Elsevier
shingle_catch_all_3 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
0925-4005
09254005
Elsevier
shingle_catch_all_4 Cho, W.-I.
Yi, C.-W.
Ju, J.-B.
Cho, B.-W.
Yun, K.-S.
Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
0925-4005
09254005
Elsevier
shingle_title_1 Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
shingle_title_2 Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
shingle_title_3 Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
shingle_title_4 Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
sigel_instance_filter dkfz
geomar
wilbert
ipn
albert
fhp
source_archive Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
timestamp 2024-05-06T08:43:28.410Z
titel Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
titel_suche Characteristics of a thin-film LaF"3 solid electrolyte for oxygen sensing
A solid electrolyte oxygen sensor has been prepared by the implementation of r.f. magnetron sputtering and electron-beam evaporation methods. Thin films of LaF"3 are applied as F^- ion-conducting solid electrolytes and a sensing electrode made of platinum black or an electron-beam evaporated Pt film is coated on the surface of the solid electrolytes. Co-sputtered Sn-SnF"2 films or electron-beam evaporated Sn/SnF"2 multilayered films are used as a reference electrode. The potential of the sensing electrode relative to that of the reference electrode changes logarithmically with the dissolved oxygen concentration in distilled water, but small e.m.f. changes are observed in a gas environment. The structure of LaF"3 is found to be microcrystalline when formed by electron-beam evaporation and the r.f. magnetron sputtering method. The capacitance of a thin-film type sensor has been examined with the aid of an impedance technique. When the sensor is exposed to oxygen, the capacitance value decreases because of the increase of F^- ion migration flux due to the adsorption of oxygen atoms on the sensing electrode surface.
topic V
ZN
uid nat_lic_papers_NLZ188483551