Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one
| ISSN: |
0040-4020
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798291346571657216 |
|---|---|
| autor | Font, J. Gracia, A. de March, P. |
| autorsonst | Font, J. Gracia, A. de March, P. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)86775-2 |
| datenlieferant | nat_lic_papers |
| fussnote | Treatment of methyl 2,3-pentadlenoate, 3, with bromine in carbon tetrachloride affords a complex mixture, whose main products are methyl (E)- and (Z)-3,4-dlbromo-2-pentenoate, 9 and 10, and 4-bromo-5-methyl-5H-furan-2-one, 4. The mechanism of formation of these and other minor compounds is discussed. Hydrolysis of the crude mixture in the presence of barium hydroxide affords lactone 4 in 30% overall yield. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175976759 |
| issn | 0040-4020 |
| journal_name | Tetrahedron |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 46 (1990), S. 4407-4416 |
| search_space | articles |
| shingle_author_1 | Font, J. Gracia, A. de March, P. |
| shingle_author_2 | Font, J. Gracia, A. de March, P. |
| shingle_author_3 | Font, J. Gracia, A. de March, P. |
| shingle_author_4 | Font, J. Gracia, A. de March, P. |
| shingle_catch_all_1 | Font, J. Gracia, A. de March, P. Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one 0040-4020 00404020 Elsevier |
| shingle_catch_all_2 | Font, J. Gracia, A. de March, P. Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one 0040-4020 00404020 Elsevier |
| shingle_catch_all_3 | Font, J. Gracia, A. de March, P. Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one 0040-4020 00404020 Elsevier |
| shingle_catch_all_4 | Font, J. Gracia, A. de March, P. Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one 0040-4020 00404020 Elsevier |
| shingle_title_1 | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one |
| shingle_title_2 | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one |
| shingle_title_3 | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one |
| shingle_title_4 | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:31:10.347Z |
| titel | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one |
| titel_suche | Reaction of methyl 2,3-pentadienoate with bromine. Preparation of 4-bromo-5-methyl-5H-furan-2-one Treatment of methyl 2,3-pentadlenoate, 3, with bromine in carbon tetrachloride affords a complex mixture, whose main products are methyl (E)- and (Z)-3,4-dlbromo-2-pentenoate, 9 and 10, and 4-bromo-5-methyl-5H-furan-2-one, 4. The mechanism of formation of these and other minor compounds is discussed. Hydrolysis of the crude mixture in the presence of barium hydroxide affords lactone 4 in 30% overall yield. |
| topic | V |
| uid | nat_lic_papers_NLZ175976759 |