Solvent dependence of the synthesis and reactions of acetyl hypofluorite
| ISSN: |
0022-1139
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
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| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798290982144311296 |
|---|---|
| autor | Rozen, S. Bareket, Y. Kol, M. |
| autorsonst | Rozen, S. Bareket, Y. Kol, M. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/S0022-1139(00)80424-8 |
| datenlieferant | nat_lic_papers |
| fussnote | Acetyl hypofluorite (AcOF) has been previously prepared using CFCl"3 (CFC-11) as a solvent. It was found that acetonitrile can replace trichlorofluoromethane without sacrificing the efficiency and the regio- and stereo-selectivity of the addition of AcOF to olefins. Most other solvents tested proved to be inadequate for the synthesis of AcOF, despite the fact that fluorine does react with the dispersed sodium acetate present in the solvent. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175678863 |
| issn | 0022-1139 |
| journal_name | Journal of Fluorine Chemistry |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 61 (1993), S. 141-146 |
| search_space | articles |
| shingle_author_1 | Rozen, S. Bareket, Y. Kol, M. |
| shingle_author_2 | Rozen, S. Bareket, Y. Kol, M. |
| shingle_author_3 | Rozen, S. Bareket, Y. Kol, M. |
| shingle_author_4 | Rozen, S. Bareket, Y. Kol, M. |
| shingle_catch_all_1 | Rozen, S. Bareket, Y. Kol, M. Solvent dependence of the synthesis and reactions of acetyl hypofluorite 0022-1139 00221139 Elsevier |
| shingle_catch_all_2 | Rozen, S. Bareket, Y. Kol, M. Solvent dependence of the synthesis and reactions of acetyl hypofluorite 0022-1139 00221139 Elsevier |
| shingle_catch_all_3 | Rozen, S. Bareket, Y. Kol, M. Solvent dependence of the synthesis and reactions of acetyl hypofluorite 0022-1139 00221139 Elsevier |
| shingle_catch_all_4 | Rozen, S. Bareket, Y. Kol, M. Solvent dependence of the synthesis and reactions of acetyl hypofluorite 0022-1139 00221139 Elsevier |
| shingle_title_1 | Solvent dependence of the synthesis and reactions of acetyl hypofluorite |
| shingle_title_2 | Solvent dependence of the synthesis and reactions of acetyl hypofluorite |
| shingle_title_3 | Solvent dependence of the synthesis and reactions of acetyl hypofluorite |
| shingle_title_4 | Solvent dependence of the synthesis and reactions of acetyl hypofluorite |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:25:21.937Z |
| titel | Solvent dependence of the synthesis and reactions of acetyl hypofluorite |
| titel_suche | Solvent dependence of the synthesis and reactions of acetyl hypofluorite Acetyl hypofluorite (AcOF) has been previously prepared using CFCl"3 (CFC-11) as a solvent. It was found that acetonitrile can replace trichlorofluoromethane without sacrificing the efficiency and the regio- and stereo-selectivity of the addition of AcOF to olefins. Most other solvents tested proved to be inadequate for the synthesis of AcOF, despite the fact that fluorine does react with the dispersed sodium acetate present in the solvent. |
| topic | V |
| uid | nat_lic_papers_NLZ175678863 |