Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis
| ISSN: |
0022-328X
|
|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798291081964552192 |
|---|---|
| autor | Lauer, M. Samuel, O. Kagan, H.B. |
| autorsonst | Lauer, M. Samuel, O. Kagan, H.B. |
| book_url | http://dx.doi.org/10.1016/S0022-328X(00)92357-X |
| datenlieferant | nat_lic_papers |
| fussnote | A chiral 1,2-diphosphine was prepared in two steps from ()-α-phellandrene. This phosphine phellanphos gives a cationic rhodium complex (phellanphos-cyclooctadienerhodium hexafluorophosphate) which catalyses asymmetric reductions. N-Acetylphenylalanine and N-acetylalanine have been prepared in 94-95% enantiomeric excess. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175407886 |
| issn | 0022-328X |
| journal_name | Journal of Organometallic Chemistry |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 177 (1979), S. 309-312 |
| search_space | articles |
| shingle_author_1 | Lauer, M. Samuel, O. Kagan, H.B. |
| shingle_author_2 | Lauer, M. Samuel, O. Kagan, H.B. |
| shingle_author_3 | Lauer, M. Samuel, O. Kagan, H.B. |
| shingle_author_4 | Lauer, M. Samuel, O. Kagan, H.B. |
| shingle_catch_all_1 | Lauer, M. Samuel, O. Kagan, H.B. Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis 0022-328X 0022328X Elsevier |
| shingle_catch_all_2 | Lauer, M. Samuel, O. Kagan, H.B. Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis 0022-328X 0022328X Elsevier |
| shingle_catch_all_3 | Lauer, M. Samuel, O. Kagan, H.B. Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis 0022-328X 0022328X Elsevier |
| shingle_catch_all_4 | Lauer, M. Samuel, O. Kagan, H.B. Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis 0022-328X 0022328X Elsevier |
| shingle_title_1 | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis |
| shingle_title_2 | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis |
| shingle_title_3 | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis |
| shingle_title_4 | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:26:57.837Z |
| titel | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis |
| titel_suche | Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis A chiral 1,2-diphosphine was prepared in two steps from ()-α-phellandrene. This phosphine phellanphos gives a cationic rhodium complex (phellanphos-cyclooctadienerhodium hexafluorophosphate) which catalyses asymmetric reductions. N-Acetylphenylalanine and N-acetylalanine have been prepared in 94-95% enantiomeric excess. |
| topic | V |
| uid | nat_lic_papers_NLZ175407886 |