Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2
| ISSN: |
0277-5387
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
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| Topics: |
Chemistry and Pharmacology
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798291750428606465 |
|---|---|
| autor | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| autorsonst | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)84857-3 |
| datenlieferant | nat_lic_papers |
| fussnote | Prolonged reaction of CF"3COOH with Mo(CO)"3(P(OCH"3)"3)"3 in CH"2Cl"2 yields the dimer [Mo(CO)"2(μ(O)P(OCH"3)"2)P(OCH"3)"3CF"3COO]"2 in low yield. The complex has been characterized by the usual spectroscopic methods and by an X-ray crystal structure determination. The molybdenum atoms are linked by two OP bridges, the six-membered dimetallacycle adopting a twisted-boat conformation. Each molybdenum is seven-coordinated and has a capped trigonal prism geometry, the capping position being occupied by an oxygen atom of the bridging OP(OCH"3)"2 group. A mechanism similar to the well-known Michaelis-Arbuzov rearrangement is proposed and substantiated by the concomitant apparition of CF"3COOCH"3 during the reaction. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175195684 |
| issn | 0277-5387 |
| journal_name | Polyhedron |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 5 (1986), S. 1785-1789 |
| search_space | articles |
| shingle_author_1 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| shingle_author_2 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| shingle_author_3 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| shingle_author_4 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. |
| shingle_catch_all_1 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 0277-5387 02775387 Elsevier |
| shingle_catch_all_2 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 0277-5387 02775387 Elsevier |
| shingle_catch_all_3 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 0277-5387 02775387 Elsevier |
| shingle_catch_all_4 | Arabi, S. Berthelot, C. Barry, J.-P. Taylor, N.J. Chaudret, B. Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 0277-5387 02775387 Elsevier |
| shingle_title_1 | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 |
| shingle_title_2 | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 |
| shingle_title_3 | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 |
| shingle_title_4 | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:37:35.629Z |
| titel | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 |
| titel_suche | Unexpected preparation and X-ray crystal structure of the dinuclear complex Mo"2(μ-P(O)(OCH"3)"2)"2(CO)"4(P(OCH"3)"3)"2(CF"3COO)"2 Prolonged reaction of CF"3COOH with Mo(CO)"3(P(OCH"3)"3)"3 in CH"2Cl"2 yields the dimer [Mo(CO)"2(μ(O)P(OCH"3)"2)P(OCH"3)"3CF"3COO]"2 in low yield. The complex has been characterized by the usual spectroscopic methods and by an X-ray crystal structure determination. The molybdenum atoms are linked by two OP bridges, the six-membered dimetallacycle adopting a twisted-boat conformation. Each molybdenum is seven-coordinated and has a capped trigonal prism geometry, the capping position being occupied by an oxygen atom of the bridging OP(OCH"3)"2 group. A mechanism similar to the well-known Michaelis-Arbuzov rearrangement is proposed and substantiated by the concomitant apparition of CF"3COOCH"3 during the reaction. |
| topic | V |
| uid | nat_lic_papers_NLZ175195684 |