Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety
| ISSN: |
0022-328X
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|---|---|
| Keywords: |
Azobenzonorbornadiene ; Carbonyl ; Coupling ; Cyclohexane ; Iron ; Stereospecific
|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798291080662220800 |
|---|---|
| autor | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| autorsonst | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0022-328X(94)85023-2 |
| datenlieferant | nat_lic_papers |
| fussnote | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes 1 and cyclohexene occurs thermally and photochemically. Complexes 2 were formed stereospecifically with a yield of 21-34% via C-C bond formation from the exo-face of 7-ABND accompanied by the generation of (^4η-cyclohexadiene)Fe(CO)"3 moieties with Fe(CO)"3 syn to the new C-C bond. At the same time, C-5 of this moiety was functionalized with a bulky 7-ABND heterocycle. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175172854 |
| issn | 0022-328X |
| journal_name | Journal of Organometallic Chemistry |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 481 (1994), S. 179-181 |
| schlagwort | Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific |
| search_space | articles |
| shingle_author_1 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| shingle_author_2 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| shingle_author_3 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| shingle_author_4 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. |
| shingle_catch_all_1 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific 0022-328X 0022328X Elsevier |
| shingle_catch_all_2 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific 0022-328X 0022328X Elsevier |
| shingle_catch_all_3 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific 0022-328X 0022328X Elsevier |
| shingle_catch_all_4 | Sun, C.-H. Shang, N.-C. Liou, L.-S. Wang, J.-C. Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific Azobenzonorbornadiene Carbonyl Coupling Cyclohexane Iron Stereospecific 0022-328X 0022328X Elsevier |
| shingle_title_1 | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety |
| shingle_title_2 | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety |
| shingle_title_3 | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety |
| shingle_title_4 | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:26:56.347Z |
| titel | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety |
| titel_suche | Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes and cyclohexene to form stereospecifically a (C-5 substituted η^4-cyclohexadiene)Fe(CO)"3 moiety Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron complexes 1 and cyclohexene occurs thermally and photochemically. Complexes 2 were formed stereospecifically with a yield of 21-34% via C-C bond formation from the exo-face of 7-ABND accompanied by the generation of (^4η-cyclohexadiene)Fe(CO)"3 moieties with Fe(CO)"3 syn to the new C-C bond. At the same time, C-5 of this moiety was functionalized with a bulky 7-ABND heterocycle. |
| topic | V |
| uid | nat_lic_papers_NLZ175172854 |