Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
ISSN: |
0022-328X
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Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
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Topics: |
Chemistry and Pharmacology
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Type of Medium: |
Electronic Resource
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URL: |
_version_ | 1798291074471428096 |
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autor | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
autorsonst | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
book_url | http://linkinghub.elsevier.com/retrieve/pii/0022-328X(90)85413-S |
datenlieferant | nat_lic_papers |
fussnote | Treatment of [Fe"2(CO)"6(μ-CO)(μ-CRCR'H)]^- (R = R' = Ph, H an RPh, R' = Me) with PPh"2Cl in CH"2Cl"2 in the presence of TlBF"4 gives complexes of the type [Fe"2(CO)"6(μ-PPh"2)(μ-CRCR'H)], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe"2(CO)"6(μ-CO)(μ-PPh"2)]^- with CF"3COOH and acetylenes. The crystal structure of the complex [Fe"2(CO)"6(μ-PPh"2)(μ-CPHCPhH)] is reported. |
hauptsatz | hsatz_simple |
identnr | NLZ175118558 |
issn | 0022-328X |
journal_name | Journal of Organometallic Chemistry |
materialart | 1 |
package_name | Elsevier |
publikationsort | Amsterdam |
publisher | Elsevier |
reference | 389 (1990), S. 219-226 |
search_space | articles |
shingle_author_1 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
shingle_author_2 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
shingle_author_3 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
shingle_author_4 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. |
shingle_catch_all_1 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] 0022-328X 0022328X Elsevier |
shingle_catch_all_2 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] 0022-328X 0022328X Elsevier |
shingle_catch_all_3 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] 0022-328X 0022328X Elsevier |
shingle_catch_all_4 | Yanez, R. Ros, J. Mathieu, R. Solans, X. Font-Bardia, M. Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] 0022-328X 0022328X Elsevier |
shingle_title_1 | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] |
shingle_title_2 | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] |
shingle_title_3 | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] |
shingle_title_4 | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] |
sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
timestamp | 2024-05-06T08:26:50.954Z |
titel | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] |
titel_suche | Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)] Treatment of [Fe"2(CO)"6(μ-CO)(μ-CRCR'H)]^- (R = R' = Ph, H an RPh, R' = Me) with PPh"2Cl in CH"2Cl"2 in the presence of TlBF"4 gives complexes of the type [Fe"2(CO)"6(μ-PPh"2)(μ-CRCR'H)], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe"2(CO)"6(μ-CO)(μ-PPh"2)]^- with CF"3COOH and acetylenes. The crystal structure of the complex [Fe"2(CO)"6(μ-PPh"2)(μ-CPHCPhH)] is reported. |
topic | V |
uid | nat_lic_papers_NLZ175118558 |