Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]

Yanez, R. ; Ros, J. ; Mathieu, R. ; Solans, X. ; Font-Bardia, M.

Amsterdam : Elsevier
ISSN:
0022-328X
Source:
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
Topics:
Chemistry and Pharmacology
Type of Medium:
Electronic Resource
URL:
_version_ 1798291074471428096
autor Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
autorsonst Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
book_url http://linkinghub.elsevier.com/retrieve/pii/0022-328X(90)85413-S
datenlieferant nat_lic_papers
fussnote Treatment of [Fe"2(CO)"6(μ-CO)(μ-CRCR'H)]^- (R = R' = Ph, H an RPh, R' = Me) with PPh"2Cl in CH"2Cl"2 in the presence of TlBF"4 gives complexes of the type [Fe"2(CO)"6(μ-PPh"2)(μ-CRCR'H)], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe"2(CO)"6(μ-CO)(μ-PPh"2)]^- with CF"3COOH and acetylenes. The crystal structure of the complex [Fe"2(CO)"6(μ-PPh"2)(μ-CPHCPhH)] is reported.
hauptsatz hsatz_simple
identnr NLZ175118558
issn 0022-328X
journal_name Journal of Organometallic Chemistry
materialart 1
package_name Elsevier
publikationsort Amsterdam
publisher Elsevier
reference 389 (1990), S. 219-226
search_space articles
shingle_author_1 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
shingle_author_2 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
shingle_author_3 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
shingle_author_4 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
shingle_catch_all_1 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
0022-328X
0022328X
Elsevier
shingle_catch_all_2 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
0022-328X
0022328X
Elsevier
shingle_catch_all_3 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
0022-328X
0022328X
Elsevier
shingle_catch_all_4 Yanez, R.
Ros, J.
Mathieu, R.
Solans, X.
Font-Bardia, M.
Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
0022-328X
0022328X
Elsevier
shingle_title_1 Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
shingle_title_2 Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
shingle_title_3 Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
shingle_title_4 Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
sigel_instance_filter dkfz
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wilbert
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source_archive Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
timestamp 2024-05-06T08:26:50.954Z
titel Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
titel_suche Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe"2(CO)"6(μ-PPh"2(μ-CPhCPhH)]
Treatment of [Fe"2(CO)"6(μ-CO)(μ-CRCR'H)]^- (R = R' = Ph, H an RPh, R' = Me) with PPh"2Cl in CH"2Cl"2 in the presence of TlBF"4 gives complexes of the type [Fe"2(CO)"6(μ-PPh"2)(μ-CRCR'H)], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe"2(CO)"6(μ-CO)(μ-PPh"2)]^- with CF"3COOH and acetylenes. The crystal structure of the complex [Fe"2(CO)"6(μ-PPh"2)(μ-CPHCPhH)] is reported.
topic V
uid nat_lic_papers_NLZ175118558