Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls
| ISSN: |
0022-328X
|
|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798291068113911808 |
|---|---|
| autor | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| autorsonst | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0022-328X(85)80340-5 |
| datenlieferant | nat_lic_papers |
| fussnote | A new method of synthesis of η^5-pyrrolyltricarbonylmanganese(I) is reported, along with the first syntheses of η^5-indolyltricarbonylmanganese(I) and of η^5-1- pyrindinyltricarbonylmanganese(I). Kinetic studies on CO substitution reactions of these η^5-N-heterocyclic manganese carbonyls show that the reactions take place by a second-order process, first-order in metal complex and first-order in nucleophile. The most significant observation is that the N-heterocyclic compounds react faster than do their carbocyclic counterparts. This anticipated result is consistent with the greater electron-withdrawing ability of the N systems in the transition state for reaction, because N is more electronegative than is C. |
| hauptsatz | hsatz_simple |
| identnr | NLZ175056722 |
| issn | 0022-328X |
| journal_name | Journal of Organometallic Chemistry |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 296 (1985), S. 83-94 |
| search_space | articles |
| shingle_author_1 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| shingle_author_2 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| shingle_author_3 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| shingle_author_4 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. |
| shingle_catch_all_1 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls 0022-328X 0022328X Elsevier |
| shingle_catch_all_2 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls 0022-328X 0022328X Elsevier |
| shingle_catch_all_3 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls 0022-328X 0022328X Elsevier |
| shingle_catch_all_4 | Ji, L.-N. Kershner, D.L. Rerek, M.E. Basolo, F. Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls 0022-328X 0022328X Elsevier |
| shingle_title_1 | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls |
| shingle_title_2 | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls |
| shingle_title_3 | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls |
| shingle_title_4 | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:26:44.203Z |
| titel | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls |
| titel_suche | Syntheses and carbon monoxide substitution reactions of η^5-N-heterocycle manganese tricarbonyls A new method of synthesis of η^5-pyrrolyltricarbonylmanganese(I) is reported, along with the first syntheses of η^5-indolyltricarbonylmanganese(I) and of η^5-1- pyrindinyltricarbonylmanganese(I). Kinetic studies on CO substitution reactions of these η^5-N-heterocyclic manganese carbonyls show that the reactions take place by a second-order process, first-order in metal complex and first-order in nucleophile. The most significant observation is that the N-heterocyclic compounds react faster than do their carbocyclic counterparts. This anticipated result is consistent with the greater electron-withdrawing ability of the N systems in the transition state for reaction, because N is more electronegative than is C. |
| topic | V |
| uid | nat_lic_papers_NLZ175056722 |