The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione
| ISSN: |
0022-2860
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
Physics
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798291048964816897 |
|---|---|
| autor | Iqbal, K. Owen, N.L. Sheridan, J. |
| autorsonst | Iqbal, K. Owen, N.L. Sheridan, J. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0022-2860(80)80123-2 |
| datenlieferant | nat_lic_papers |
| fussnote | Rotational and centrifugal distortion constants are determined for the ground state and several excited states of the lowest vibrational mode of l,3-dioxole-2-thione, the ''envelope'' ring-bending mode. The structure of the molecule is planar. The A-constant is 1% larger than that of 1,3-dioxole-2-one (vinylene carbonate), which indicates small changes in ring-geometry on substituting CS for CO. The dipole moment of 1,3-dioxole-2-thione deduced from Stark-effect measurements is (1.60 +/- 0.02) x 10^-^2^9 Cm (4.81 +/- 0.06 D). IR and Raman spectra lead to a complete analysis of the normal modes of vibration, based partially on a normal coordinate calculation. |
| hauptsatz | hsatz_simple |
| identnr | NLZ174503571 |
| issn | 0022-2860 |
| journal_name | Journal of Molecular Structure |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 64 (1980), S. 137-147 |
| search_space | articles |
| shingle_author_1 | Iqbal, K. Owen, N.L. Sheridan, J. |
| shingle_author_2 | Iqbal, K. Owen, N.L. Sheridan, J. |
| shingle_author_3 | Iqbal, K. Owen, N.L. Sheridan, J. |
| shingle_author_4 | Iqbal, K. Owen, N.L. Sheridan, J. |
| shingle_catch_all_1 | Iqbal, K. Owen, N.L. Sheridan, J. The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione 0022-2860 00222860 Elsevier |
| shingle_catch_all_2 | Iqbal, K. Owen, N.L. Sheridan, J. The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione 0022-2860 00222860 Elsevier |
| shingle_catch_all_3 | Iqbal, K. Owen, N.L. Sheridan, J. The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione 0022-2860 00222860 Elsevier |
| shingle_catch_all_4 | Iqbal, K. Owen, N.L. Sheridan, J. The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione 0022-2860 00222860 Elsevier |
| shingle_title_1 | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione |
| shingle_title_2 | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione |
| shingle_title_3 | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione |
| shingle_title_4 | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:26:26.803Z |
| titel | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione |
| titel_suche | The rotational and vibrational spectra, structure and dipole moment of 1,3-dioxole-2-thione Rotational and centrifugal distortion constants are determined for the ground state and several excited states of the lowest vibrational mode of l,3-dioxole-2-thione, the ''envelope'' ring-bending mode. The structure of the molecule is planar. The A-constant is 1% larger than that of 1,3-dioxole-2-one (vinylene carbonate), which indicates small changes in ring-geometry on substituting CS for CO. The dipole moment of 1,3-dioxole-2-thione deduced from Stark-effect measurements is (1.60 +/- 0.02) x 10^-^2^9 Cm (4.81 +/- 0.06 D). IR and Raman spectra lead to a complete analysis of the normal modes of vibration, based partially on a normal coordinate calculation. |
| topic | V U |
| uid | nat_lic_papers_NLZ174503571 |