Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde
Su, F. ; Calvert, J.G. ; Shaw, J.H. ; Niki, H. ; Maker, P.D. ; Savage, C.M. ; Breitenbach, L.D.
Amsterdam : Elsevier
Amsterdam : Elsevier
| ISSN: |
0009-2614
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
Physics
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798292316551643137 |
|---|---|
| autor | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| autorsonst | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0009-2614(79)87053-0 |
| datenlieferant | nat_lic_papers |
| fussnote | Fourier transform infrared spectroscopy has been employed to study the mechanism of formaldehyde photooxidation in dilute gaseous mixtures of Cl"2 and CH"2O (ppm level) and H"2, O"2, and N"2 (P"T ~ 700 Torr), temperature, 25 +/- 2^oC. Infrared absorption bands due to a new metastable compound were observed in addition to those of the expected products: HCl, HCO"2H, CO, and H"2O"2. The transient species was tentatively identified as hydroperoxy-hydroxy-methane (HO"2CH"2OH), which was presumably formed through the reaction, HO"2 + O"2CH"2OH -〉 HO"2CH"2OH + O"2. |
| hauptsatz | hsatz_simple |
| identnr | NLZ17389366X |
| issn | 0009-2614 |
| journal_name | Chemical Physics Letters |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 65 (1979), S. 221-225 |
| search_space | articles |
| shingle_author_1 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| shingle_author_2 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| shingle_author_3 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| shingle_author_4 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. |
| shingle_catch_all_1 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde 0009-2614 00092614 Elsevier |
| shingle_catch_all_2 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde 0009-2614 00092614 Elsevier |
| shingle_catch_all_3 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde 0009-2614 00092614 Elsevier |
| shingle_catch_all_4 | Su, F. Calvert, J.G. Shaw, J.H. Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.D. Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde 0009-2614 00092614 Elsevier |
| shingle_title_1 | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde |
| shingle_title_2 | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde |
| shingle_title_3 | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde |
| shingle_title_4 | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:46:35.337Z |
| titel | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde |
| titel_suche | Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde Fourier transform infrared spectroscopy has been employed to study the mechanism of formaldehyde photooxidation in dilute gaseous mixtures of Cl"2 and CH"2O (ppm level) and H"2, O"2, and N"2 (P"T ~ 700 Torr), temperature, 25 +/- 2^oC. Infrared absorption bands due to a new metastable compound were observed in addition to those of the expected products: HCl, HCO"2H, CO, and H"2O"2. The transient species was tentatively identified as hydroperoxy-hydroxy-methane (HO"2CH"2OH), which was presumably formed through the reaction, HO"2 + O"2CH"2OH -〉 HO"2CH"2OH + O"2. |
| topic | V U |
| uid | nat_lic_papers_NLZ17389366X |