High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams
| ISSN: |
0009-2614
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
Physics
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798292314688323584 |
|---|---|
| autor | Niu, B. Bai, Y. Shirley, D.A. |
| autorsonst | Niu, B. Bai, Y. Shirley, D.A. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85059-W |
| datenlieferant | nat_lic_papers |
| fussnote | High resolution helium Iα (584 Å) photoelectron spectra of H"2CCO and D"2CCO using supersonic molecular beams are reported. The adiabatic ionization energies (AIEs) of the electronic first, second, and fifth excited states are determined unambiguously. The doublet-like fine structures observed in the first excited states of ketene imply the excitation of a ''soft'' mode that was not observed before. Strong isotope effects are observed in the vibronic (vibrational) couplings in the ground state of ketene cations. The AIEs and spectroscopic constants for all six ionic states are reported to a much higher accuracy than previously available. |
| hauptsatz | hsatz_simple |
| identnr | NLZ173872247 |
| issn | 0009-2614 |
| journal_name | Chemical Physics Letters |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 201 (1993), S. 217-222 |
| search_space | articles |
| shingle_author_1 | Niu, B. Bai, Y. Shirley, D.A. |
| shingle_author_2 | Niu, B. Bai, Y. Shirley, D.A. |
| shingle_author_3 | Niu, B. Bai, Y. Shirley, D.A. |
| shingle_author_4 | Niu, B. Bai, Y. Shirley, D.A. |
| shingle_catch_all_1 | Niu, B. Bai, Y. Shirley, D.A. High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams 0009-2614 00092614 Elsevier |
| shingle_catch_all_2 | Niu, B. Bai, Y. Shirley, D.A. High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams 0009-2614 00092614 Elsevier |
| shingle_catch_all_3 | Niu, B. Bai, Y. Shirley, D.A. High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams 0009-2614 00092614 Elsevier |
| shingle_catch_all_4 | Niu, B. Bai, Y. Shirley, D.A. High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams 0009-2614 00092614 Elsevier |
| shingle_title_1 | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams |
| shingle_title_2 | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams |
| shingle_title_3 | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams |
| shingle_title_4 | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:46:33.621Z |
| titel | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams |
| titel_suche | High resolution He Iα photoelectron spectroscopy of H"2CCO and D"2CCO using supersonic molecular beams High resolution helium Iα (584 Å) photoelectron spectra of H"2CCO and D"2CCO using supersonic molecular beams are reported. The adiabatic ionization energies (AIEs) of the electronic first, second, and fifth excited states are determined unambiguously. The doublet-like fine structures observed in the first excited states of ketene imply the excitation of a ''soft'' mode that was not observed before. Strong isotope effects are observed in the vibronic (vibrational) couplings in the ground state of ketene cations. The AIEs and spectroscopic constants for all six ionic states are reported to a much higher accuracy than previously available. |
| topic | V U |
| uid | nat_lic_papers_NLZ173872247 |