Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy
| ISSN: |
0009-2614
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
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| Topics: |
Chemistry and Pharmacology
Physics
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798292307111313410 |
|---|---|
| autor | Forster, T. Volker, S. |
| autorsonst | Forster, T. Volker, S. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0009-2614(75)80188-6 |
| datenlieferant | nat_lic_papers |
| fussnote | A quantitative study is presented of the proton transfer reactions which follow the dissociation of the 8-hydroxypyrene-1,3,6-trisulphonic acid ion ROH by flash photolysis in aqueous solution. The value of the rate constant k"1 = 1.9 x 10^1^1 M^-^1 s^-^1 is in agreement with the Debye theory for diffusion controlled reactions. The rate constant k"2 is determined for a series of neutral acids AH (maleic, acetic, phenylacetic, benzoic, formic, chloroacetic, and bromoacetic acid) added to the solution. For the weaker acids (pK 〉 4.25) the value of log k"2 is porportional to that of pK; for those with pK 〈 4.25 a limiting value k"2 = 3.6 x 10^9 M^-^1 s^-^1 is reached. |
| hauptsatz | hsatz_simple |
| identnr | NLZ173809499 |
| issn | 0009-2614 |
| journal_name | Chemical Physics Letters |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 34 (1975), S. 1-6 |
| search_space | articles |
| shingle_author_1 | Forster, T. Volker, S. |
| shingle_author_2 | Forster, T. Volker, S. |
| shingle_author_3 | Forster, T. Volker, S. |
| shingle_author_4 | Forster, T. Volker, S. |
| shingle_catch_all_1 | Forster, T. Volker, S. Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy 0009-2614 00092614 Elsevier |
| shingle_catch_all_2 | Forster, T. Volker, S. Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy 0009-2614 00092614 Elsevier |
| shingle_catch_all_3 | Forster, T. Volker, S. Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy 0009-2614 00092614 Elsevier |
| shingle_catch_all_4 | Forster, T. Volker, S. Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy 0009-2614 00092614 Elsevier |
| shingle_title_1 | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy |
| shingle_title_2 | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy |
| shingle_title_3 | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy |
| shingle_title_4 | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:46:26.455Z |
| titel | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy |
| titel_suche | Kinetics of proton transfer reactions involving hydroxypyrene-trisulphonate in aqueous solution by nanosecond laser absorption spectroscopy A quantitative study is presented of the proton transfer reactions which follow the dissociation of the 8-hydroxypyrene-1,3,6-trisulphonic acid ion ROH by flash photolysis in aqueous solution. The value of the rate constant k"1 = 1.9 x 10^1^1 M^-^1 s^-^1 is in agreement with the Debye theory for diffusion controlled reactions. The rate constant k"2 is determined for a series of neutral acids AH (maleic, acetic, phenylacetic, benzoic, formic, chloroacetic, and bromoacetic acid) added to the solution. For the weaker acids (pK 〉 4.25) the value of log k"2 is porportional to that of pK; for those with pK 〈 4.25 a limiting value k"2 = 3.6 x 10^9 M^-^1 s^-^1 is reached. |
| topic | V U |
| uid | nat_lic_papers_NLZ173809499 |