Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O
| ISSN: |
0009-2614
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|---|---|
| Source: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
|
| Topics: |
Chemistry and Pharmacology
Physics
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798292302711488512 |
|---|---|
| autor | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| autorsonst | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| book_url | http://linkinghub.elsevier.com/retrieve/pii/0009-2614(80)80571-9 |
| datenlieferant | nat_lic_papers |
| fussnote | Two O-H stretch bands at 3647.5 and 3598.3 cm^-^1 have been observed for the previously reported ''metastable species'' formed by HO"2-CH"2O interactions. These bands are consistent with the presence of an OH and an OOH group and provide support for the earlier tentative identification of hydroperoxy-hydroxy-methane, CH"2(OH)OOH, formed via CH"2O + HO"2 -〉 CH"2(OH)OO, CH"2(OH)OO + HO"2 -〉 CH"2(OH)OOH + O"2. This compound is relatively stable in the dark at 25^oC. |
| hauptsatz | hsatz_simple |
| identnr | NLZ173771920 |
| issn | 0009-2614 |
| journal_name | Chemical Physics Letters |
| materialart | 1 |
| package_name | Elsevier |
| publikationsort | Amsterdam |
| publisher | Elsevier |
| reference | 75 (1980), S. 533-535 |
| search_space | articles |
| shingle_author_1 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| shingle_author_2 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| shingle_author_3 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| shingle_author_4 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. |
| shingle_catch_all_1 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O 0009-2614 00092614 Elsevier |
| shingle_catch_all_2 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O 0009-2614 00092614 Elsevier |
| shingle_catch_all_3 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O 0009-2614 00092614 Elsevier |
| shingle_catch_all_4 | Niki, H. Maker, P.D. Savage, C.M. Breitenbach, L.P. Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O 0009-2614 00092614 Elsevier |
| shingle_title_1 | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O |
| shingle_title_2 | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O |
| shingle_title_3 | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O |
| shingle_title_4 | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
| timestamp | 2024-05-06T08:46:22.114Z |
| titel | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O |
| titel_suche | Further IR spectroscopic evidence for the formation of CH"2(OH)OOH in the gas-phase reaction of HO"2 with CH"2O Two O-H stretch bands at 3647.5 and 3598.3 cm^-^1 have been observed for the previously reported ''metastable species'' formed by HO"2-CH"2O interactions. These bands are consistent with the presence of an OH and an OOH group and provide support for the earlier tentative identification of hydroperoxy-hydroxy-methane, CH"2(OH)OOH, formed via CH"2O + HO"2 -〉 CH"2(OH)OO, CH"2(OH)OO + HO"2 -〉 CH"2(OH)OOH + O"2. This compound is relatively stable in the dark at 25^oC. |
| topic | V U |
| uid | nat_lic_papers_NLZ173771920 |