Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition
Hayward, S. A. ; Pryde, A. K. A. ; de Dombal, R.F. ; Carpenter, M. A. ; Dove, M. T.
Springer
Published 2000
Springer
Published 2000
ISSN: |
1432-2021
|
---|---|
Keywords: |
Key words Nepheline ; Incommensurate ; Rigid unit mode
|
Source: |
Springer Online Journal Archives 1860-2000
|
Topics: |
Chemistry and Pharmacology
Geosciences
Physics
|
Notes: |
Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy.
|
Type of Medium: |
Electronic Resource
|
URL: |
_version_ | 1798295903584387073 |
---|---|
autor | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
autorsonst | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
book_url | http://dx.doi.org/10.1007/s002690050257 |
datenlieferant | nat_lic_papers |
hauptsatz | hsatz_simple |
identnr | NLM202920666 |
issn | 1432-2021 |
journal_name | Physics and chemistry of minerals |
materialart | 1 |
notes | Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. |
package_name | Springer |
publikationsjahr_anzeige | 2000 |
publikationsjahr_facette | 2000 |
publikationsjahr_intervall | 7999:2000-2004 |
publikationsjahr_sort | 2000 |
publisher | Springer |
reference | 27 (2000), S. 285-290 |
schlagwort | Key words Nepheline Incommensurate Rigid unit mode |
search_space | articles |
shingle_author_1 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
shingle_author_2 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
shingle_author_3 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
shingle_author_4 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. |
shingle_catch_all_1 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition Key words Nepheline Incommensurate Rigid unit mode Key words Nepheline Incommensurate Rigid unit mode Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. 1432-2021 14322021 Springer |
shingle_catch_all_2 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition Key words Nepheline Incommensurate Rigid unit mode Key words Nepheline Incommensurate Rigid unit mode Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. 1432-2021 14322021 Springer |
shingle_catch_all_3 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition Key words Nepheline Incommensurate Rigid unit mode Key words Nepheline Incommensurate Rigid unit mode Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. 1432-2021 14322021 Springer |
shingle_catch_all_4 | Hayward, S. A. Pryde, A. K. A. de Dombal, R.F. Carpenter, M. A. Dove, M. T. Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition Key words Nepheline Incommensurate Rigid unit mode Key words Nepheline Incommensurate Rigid unit mode Abstract Calculations of the Rigid Unit Modes (RUMs) allowed in the nepheline structure are used to explain the diffuse scattering previously seen in electron diffraction experiments. The RUM calculations also show that the modulation wavelength for incommensurate nephelines is essentially determined by the framework topology. X-ray diffraction is used to measure the intensity of the diffuse scattering as a function of temperature. The diffuse intensity increases sharply at 308 K. This effect is interpreted as being due to the softening of a phonon mode, indicating a phase transition. Measurements of this phase transition below the transition temperature are made using hard mode infrared spectroscopy. 1432-2021 14322021 Springer |
shingle_title_1 | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
shingle_title_2 | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
shingle_title_3 | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
shingle_title_4 | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
source_archive | Springer Online Journal Archives 1860-2000 |
timestamp | 2024-05-06T09:43:36.115Z |
titel | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
titel_suche | Rigid Unit Modes in disordered nepheline: a study of a displacive incommensurate phase transition |
topic | V TE-TZ U |
uid | nat_lic_papers_NLM202920666 |