The calculation of electric dipole vibronic intensities in centrosymmetric coordination compounds using the crystal field-closure-ligand polarization model
| ISSN: |
1432-2234
|
|---|---|
| Keywords: |
Vibronic intensities ; Crystal field ; Ligand polarization ; Complex ion
|
| Source: |
Springer Online Journal Archives 1860-2000
|
| Topics: |
Chemistry and Pharmacology
|
| Notes: |
Abstract Equations are derived for the evaluation of the contribution to the electric dipole vibronic intensity of d-d and f-f transitions in octahedral complex ions. Expressions for the evaluation of the crystal-field and ligand polarization terms and the cross term between are presented in symmetry adapted form and tables of the required coupling constants are given.
|
| Type of Medium: |
Electronic Resource
|
| URL: |