Osmotic coefficients of dilute aqueous solutions of unsymmetrical cobalt-amine type salts at 0°C
Arsuaga, Jesus M. ; Caceres-Alonso, Mercedes ; Baonza, Valentín G. ; Nuñez, Javier
Springer
Published 1991
Springer
Published 1991
| ISSN: |
1572-8927
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|---|---|
| Keywords: |
Osmotic coefficient ; freezing point method ; ion association ; tris-propylenediaminocobalt(III) chloride, bromide and nitrate ; tris-trimethylenediaminocobalt(III) chloride and bromide
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract The osmotic coefficients of dilute aqueous solutions of [Co(pn)3]X3 [pn=1,2-diaminopropane and X=Cl−, Br− and (NO3)−] and [Co(tn)3]X3 (tn=1,3-diaminopropane and X=Cl− and Br−) have been measured from 0.00 to 0.02 mol-kg−1 at 0°C by the freezing point method. The results have been compared with those obtained from the numerical integration of the Poisson-Boltzmann equation.
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| Type of Medium: |
Electronic Resource
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| URL: |