Conductance of lithium, sodium and potassium nitrates in acetonitrile-water and ethanol-water isodielectric mixtures at 25°C
| ISSN: |
1572-8927
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| Keywords: |
Electrolyte conductance ; single-ion conductance ; ion-pair formation ; ethanol-water ; acetonitrile-water ; isodielectric mixtures
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract Precise conductance measurements of solutions of lithium, sodium and potassium nitrates were made at 25°C in acetonitrile-water and ethanol-water isodielectric mixtures, containing up to 15 mole percent organic-solvent, and the data analyzed by the 1978–80 Fuoss conductance equations. Single ion conductances were determined with the help of transference numbers in the case of ethanol-water mixtures. Ion-pair association constants are discussed in terms of contact and solvent-separated ion-pairs and were found to be almost equal to those for the halides. The anion appears more sensitive than the cations to the solvent structure in mixtures rich in water.
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| Type of Medium: |
Electronic Resource
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| URL: |