Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures

Nakajima, T. ; Fukamachi, T. ; Terasaki, O. ; Hosoya, S.
Springer
Published 1977
ISSN:
1573-7357
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
Type of Medium:
Electronic Resource
URL:
_version_ 1798296907103076352
autor Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
autorsonst Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
book_url http://dx.doi.org/10.1007/BF00654648
datenlieferant nat_lic_papers
hauptsatz hsatz_simple
identnr NLM197724949
issn 1573-7357
journal_name Journal of low temperature physics
materialart 1
notes Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
package_name Springer
publikationsjahr_anzeige 1977
publikationsjahr_facette 1977
publikationsjahr_intervall 8024:1975-1979
publikationsjahr_sort 1977
publisher Springer
reference 27 (1977), S. 245-258
search_space articles
shingle_author_1 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
shingle_author_2 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
shingle_author_3 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
shingle_author_4 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
shingle_catch_all_1 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
1573-7357
15737357
Springer
shingle_catch_all_2 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
1573-7357
15737357
Springer
shingle_catch_all_3 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
1573-7357
15737357
Springer
shingle_catch_all_4 Nakajima, T.
Fukamachi, T.
Terasaki, O.
Hosoya, S.
Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
Abstract Differences in the lattice constants of Mo-100 and Mo-92 have been measured by x-ray diffraction, in order to search directly for the volume effect of isotopes in a superconductor. No significant difference in the lattice constanta(Mo-100)−a(Mo-92) could be detected at 290 K, while the differences −0.0014±0.0008 and −0.0029±0.0009 Å were detected at 85.3 and 4.31 K, respectively. These values, and their temperature dependence, are considered to be theoretically reasonable. The exponent α in the isotope effect defined by Tc∝M-α is represented thermodynamically by α=−(∂ lnT c /∂ lnM)−(∂ lnT c /∂ lnV)(d lnV/d lnM). From the results, d lnV/d lnM is found to be −0.033±0.009 at 4.31 K. Then, the second term representing the isotopic volume effect is estimated to be about 0.09, with ∂ lnT c /∂ lnV≃2.81. The observed value of α is 0.33, so that the contribution of the second term, 0.09, is 27% of the value of α. It becomes quite clear that the isotopic volume effect in superconducting Mo should not be neglected.
1573-7357
15737357
Springer
shingle_title_1 Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
shingle_title_2 Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
shingle_title_3 Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
shingle_title_4 Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
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source_archive Springer Online Journal Archives 1860-2000
timestamp 2024-05-06T09:59:33.239Z
titel Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
titel_suche Experimental confirmation of the isotopic volume effect in superconducting molybdenum by means of energy-dispersive x-ray diffration at low temperatures
topic U
uid nat_lic_papers_NLM197724949