Crystal structure of (diphenyl)(morpholino)phosphiniminocyclotrithiazene
Srinivas, J. ; Murthy, G. Sreenivasa ; Thomas, C. J. ; Rao, M. N. Sudheendra
Springer
Published 1996
Springer
Published 1996
| ISSN: |
1572-8854
|
|---|---|
| Keywords: |
Cyclotrithiazene ; arylaminophospine ; crystal structure
|
| Source: |
Springer Online Journal Archives 1860-2000
|
| Topics: |
Geosciences
Physics
|
| Notes: |
Abstract The title compound (C6H5)2(OC4H8N)P=N−S3N3 crystallizes in the space group $$P\bar 1$$ with unit cell parametersa=9.3900(2),b=9.4747(1),c=11.3850(3) Å, α=95.73(4), β=96.85(6), γ=104.26(2)o, and Z=2. The tricoordinated sulfur of the cyclotrithiazene ring deviates from the mean plane of other skeletal atoms by 0.683(4) Å. The angle at this atom is the smallest in the ring and is enclosed by the longest S−N bonds observed in the ring.
|
| Type of Medium: |
Electronic Resource
|
| URL: |