A Mössbauer study on remarkable changes in chemical states of iron in silica-supported Pd-Fe bimetallic catalysts by varying Fe contents
| ISSN: |
1588-2780
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
Energy, Environment Protection, Nuclear Power Engineering
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| Notes: |
Abstract Fe-57 Mössbauer spectra of silica-supported Pd−Fe bimetallic catalysts show remarkable changes with varying Fe/Pd atomic ratios. From the spectra, the main Fe-component is estimated as highly dispersed Fe in the Fe/Pd range of 0.05–0.3 and α-Fe ensemble and Fe−Pd intermetallics in the Fe/Pd range above 0.3. It is suggested that the chemical state of iron is associated with the catalytic performance in effective CO−H2 conversion to methanol.
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| Type of Medium: |
Electronic Resource
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| URL: |