Vertical Column Abundances of COF2 Above the Jungfraujoch Station, Derived from Ground-Based Infrared Solar Observations

ISSN:
1573-0662
Keywords:
carbonyl fluoride ; IR observations ; atmospheric composition
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Geosciences
Notes:
Abstract Total vertical column abundances of carbonyl fluoride (COF2) have been derived from observations made at the International Scientific Station of the Jungfraujoch (ISSJ; altitude 3.58 km, latitude 46.5°N, longitude 8.0°E), Switzerland. A systematic analysis of two microwindows containing lines of the ν1 band was performed, based on a large set of high resolution infrared solar absorption spectra recorded with Fourier transform spectrometers, from 1985 to 1995. Examination of the whole available database indicates a significant increase of the burden of COF2 during the 1988–1995 period. The average exponential rate and the average linear rate referenced to 1992, calculated from daily mean measurements, are both equal to (4.0 ± 0.5)% yr-1 (one σ error). The results are also evaluated and discussed within the context of seasonal variability and correlation between carbonyl fluoride and hydrogen fluoride (HF) columns above the ISSJ.
Type of Medium:
Electronic Resource
URL: