Effect of surface conditioning on zinc nucleation using aluminium cathodes

Xue, T. ; Cooper, W. C. ; Pascual, R. ; Saimoto, S.
Springer
Published 1991
ISSN:
1572-8838
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
Type of Medium:
Electronic Resource
URL:
_version_ 1798296401432543232
autor Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
autorsonst Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
book_url http://dx.doi.org/10.1007/BF01052576
datenlieferant nat_lic_papers
hauptsatz hsatz_simple
identnr NLM19329995X
issn 1572-8838
journal_name Journal of applied electrochemistry
materialart 1
notes Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
package_name Springer
publikationsjahr_anzeige 1991
publikationsjahr_facette 1991
publikationsjahr_intervall 8009:1990-1994
publikationsjahr_sort 1991
publisher Springer
reference 21 (1991), S. 231-237
search_space articles
shingle_author_1 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
shingle_author_2 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
shingle_author_3 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
shingle_author_4 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
shingle_catch_all_1 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
Effect of surface conditioning on zinc nucleation using aluminium cathodes
Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
1572-8838
15728838
Springer
shingle_catch_all_2 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
Effect of surface conditioning on zinc nucleation using aluminium cathodes
Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
1572-8838
15728838
Springer
shingle_catch_all_3 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
Effect of surface conditioning on zinc nucleation using aluminium cathodes
Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
1572-8838
15728838
Springer
shingle_catch_all_4 Xue, T.
Cooper, W. C.
Pascual, R.
Saimoto, S.
Effect of surface conditioning on zinc nucleation using aluminium cathodes
Abstract The effect of the aluminium cathode microstructure on zinc nucleation has been investigated through surface examination by SEM and cyclic voltammetry. Zinc nucleation is strongly affected by the surface preparation and impurities present in the aluminium. For chemically pure aluminium, the oxide film on the surface plays an important role during zinc nucleation and crystal growth. Thickening the barrier oxide film inhibits nucleation while a reverse effect can be obtained by thinning or removing the oxide film. In the case of a dilute aluminium with iron alloy, following anodization, the Al−Fe intermetallic phases provide conductive paths through the oxide film resulting in zinc nucleation.
1572-8838
15728838
Springer
shingle_title_1 Effect of surface conditioning on zinc nucleation using aluminium cathodes
shingle_title_2 Effect of surface conditioning on zinc nucleation using aluminium cathodes
shingle_title_3 Effect of surface conditioning on zinc nucleation using aluminium cathodes
shingle_title_4 Effect of surface conditioning on zinc nucleation using aluminium cathodes
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source_archive Springer Online Journal Archives 1860-2000
timestamp 2024-05-06T09:51:30.196Z
titel Effect of surface conditioning on zinc nucleation using aluminium cathodes
titel_suche Effect of surface conditioning on zinc nucleation using aluminium cathodes
topic V
ZN
uid nat_lic_papers_NLM19329995X