Dimerization of N-(pyrid-2-YL)- and N-(5-methylpyrid-2-YL) cyanoacetamides by the action of butylthiodibutylborane
| ISSN: |
1573-9171
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract The reaction of N-(pyrid-2-yl) and N-(5-methyipyrid-2-yl) cyanoacetamides with butylthiodibutylborane in a 2∶3 ratio leads to the formation of trinuclear complex boron compounds, the alcoholysis of which gave N,N′-di(pyrid-2-yl) 3-amino-2-cyanopent-2-ene-1,5-diamides. The latter are dimers of the starting cyanamides, which are capable of acting as hexadentate chelating agents.
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| Type of Medium: |
Electronic Resource
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| URL: |