Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization
Furman, D. B. ; Ivanov, A. O. ; Olenin, A. Yu. ; Vasil'kov, A. Yu. ; Munshieva, M. K. ; Belyankin, A. Yu. ; Lisichkin, G. V. ; Sergeev, V. A. ; Bragin, O. V.
Springer
Published 1990
Springer
Published 1990
| ISSN: |
1573-9171
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| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798297497155665920 |
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| autor | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| autorsonst | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| book_url | http://dx.doi.org/10.1007/BF00959556 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM192191845 |
| issn | 1573-9171 |
| journal_name | Russian chemical bulletin |
| materialart | 1 |
| notes | Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs. |
| package_name | Springer |
| publikationsjahr_anzeige | 1990 |
| publikationsjahr_facette | 1990 |
| publikationsjahr_intervall | 8009:1990-1994 |
| publikationsjahr_sort | 1990 |
| publisher | Springer |
| reference | 39 (1990), S. 448-451 |
| search_space | articles |
| shingle_author_1 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| shingle_author_2 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| shingle_author_3 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| shingle_author_4 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. |
| shingle_catch_all_1 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs. 1573-9171 15739171 Springer |
| shingle_catch_all_2 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs. 1573-9171 15739171 Springer |
| shingle_catch_all_3 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs. 1573-9171 15739171 Springer |
| shingle_catch_all_4 | Furman, D. B. Ivanov, A. O. Olenin, A. Yu. Vasil'kov, A. Yu. Munshieva, M. K. Belyankin, A. Yu. Lisichkin, G. V. Sergeev, V. A. Bragin, O. V. Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization Abstract When activated by Et2AlCl phosphine-containing homogeneous nickel complexes and their heterogenized analogs (HMC) formed on silochrome S-120 modified by NH2 and N(PPh2)2 groups differ significantly in their effectiveness in ethylene dimerization. The catalytic activity of Ni-HMC-Et2AlCl depends on how the HMC was formed. Ni-HMC-I obtained by ligand exchange on chemically modified silochrome is ∼5–15 times more effective than Ni-HMC-II synthesized from the gas phase. The selectivity in formation of α-olefins (σC4 + σC6) is ∼4–5 times higher in the presence of Ni-HMC than for its homogeneous analogs. 1573-9171 15739171 Springer |
| shingle_title_1 | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| shingle_title_2 | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| shingle_title_3 | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| shingle_title_4 | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Springer Online Journal Archives 1860-2000 |
| timestamp | 2024-05-06T10:08:55.428Z |
| titel | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| titel_suche | Metal complexes in catalytic conversions of olefins. 4. Heterogenization of nickel complexes on chemically modified silochrome surface; activity and selectivity in ethylene dimerization |
| topic | V |
| uid | nat_lic_papers_NLM192191845 |