Acyl and alkoxy derivatives of dicyclopentadienyltitanium and the refraction increment of the π-C5H5Ti group
Nesmeyanov, A. N. ; Nogina, O. V. ; Berlin, A. M. ; Girshovich, A. S. ; Shatalov, G. V.
Springer
Published 1961
Springer
Published 1961
| ISSN: |
1573-9171
|
|---|---|
| Source: |
Springer Online Journal Archives 1860-2000
|
| Topics: |
Chemistry and Pharmacology
|
| Notes: |
Summary 1. The following dicyclopentadienyl titanium derivatives containing acyl groups we're synthesized: 2. It was shown to be'possible to prepare monoalkoxy- and mono(aryloxy)-dicyclopentadienyltitanlum derivatives by the action of alcohols and phenols on (C5H5)2TiCl2 in presence of a tertiary amine. 3. By the action of C5H5Na on (CH3)3SiOTiCl3 we obtained (C5H5)2Ti · [OSi(CH3)3]Cl and C5H5Ti[OSi(CH3)3]3. 4. The refraction increment of the titanium-cyclopentadienyl ring group (Including the atomic refraction of titanium) was determined and found to be 35.28.
|
| Type of Medium: |
Electronic Resource
|
| URL: |