An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction
| ISSN: |
0887-6266
|
|---|---|
| Keywords: |
liquid crystalline polymers ; isotropic-smectic transition ; kinetics ; x-ray dif-fraction ; synchrotron ; Chemistry ; Polymer and Materials Science
|
| Source: |
Wiley InterScience Backfile Collection 1832-2000
|
| Topics: |
Chemistry and Pharmacology
Physics
|
| Notes: |
In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc.
|
| Additional Material: |
6 Ill.
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798297844405239808 |
|---|---|
| addmaterial | 6 Ill. |
| autor | Galli, G. Mcnamee, S. G. Ober, C. K. |
| autorsonst | Galli, G. Mcnamee, S. G. Ober, C. K. |
| book_url | http://dx.doi.org/10.1002/polb.1993.090310704 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM163957509 |
| iqvoc_descriptor_keyword | iqvoc_00000092:Materials |
| issn | 0887-6266 |
| journal_name | Journal of Polymer Science Part B: Polymer Physics |
| materialart | 1 |
| notes | In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1993 |
| publikationsjahr_facette | 1993 |
| publikationsjahr_intervall | 8009:1990-1994 |
| publikationsjahr_sort | 1993 |
| publikationsort | Bognor Regis [u.a.] |
| publisher | Wiley-Blackwell |
| reference | 31 (1993), S. 773-777 |
| schlagwort | liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science |
| search_space | articles |
| shingle_author_1 | Galli, G. Mcnamee, S. G. Ober, C. K. |
| shingle_author_2 | Galli, G. Mcnamee, S. G. Ober, C. K. |
| shingle_author_3 | Galli, G. Mcnamee, S. G. Ober, C. K. |
| shingle_author_4 | Galli, G. Mcnamee, S. G. Ober, C. K. |
| shingle_catch_all_1 | Galli, G. Mcnamee, S. G. Ober, C. K. An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc. 0887-6266 08876266 Wiley-Blackwell |
| shingle_catch_all_2 | Galli, G. Mcnamee, S. G. Ober, C. K. An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc. 0887-6266 08876266 Wiley-Blackwell |
| shingle_catch_all_3 | Galli, G. Mcnamee, S. G. Ober, C. K. An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc. 0887-6266 08876266 Wiley-Blackwell |
| shingle_catch_all_4 | Galli, G. Mcnamee, S. G. Ober, C. K. An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science liquid crystalline polymers isotropic-smectic transition kinetics x-ray dif-fraction synchrotron Chemistry Polymer and Materials Science In this work we have used synchrotron x-radiation diffraction to follow in real-time the isotropic-smoetic phase transition of a side-chain liquid crystalline polymer. The analysis of the x-ray data indicated that the transition occurs within a very narrow biphasic region. As the transition takes place, the size of the smectic regions, as indicated by the width of the diffraction peaks, changed only very slightly before impingement, suggesting a two-dimensional growth pattern. A thermal investigation of the polymer paralleling the x-ray experiments was undertaken and a kinetic analysis applied to the resulting data. Qualitative agreement with a disk-like growth of the smectic regions was found. We have shown that the overall kinetics of the isotropic-smectic transition of a side-chain polymer can be studied by x-ray diffraction permitting the evaluation of several structural parameters. © 1993 John Wiley & Sons, Inc. 0887-6266 08876266 Wiley-Blackwell |
| shingle_title_1 | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| shingle_title_2 | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| shingle_title_3 | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| shingle_title_4 | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:14:27.435Z |
| titel | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| titel_suche | An investigation of the smectic-isotropic transition in a side-chain liquid crystal polymer by synchrotron radiation x-ray diffraction |
| topic | V U |
| uid | nat_lic_papers_NLM163957509 |