Interaction of poly(vinyl acetate) radical with iron (III) complexes
| ISSN: |
0360-6376
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|---|---|
| Keywords: |
Physics ; Polymer and Materials Science
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| Source: |
Wiley InterScience Backfile Collection 1832-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C.
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| Additional Material: |
6 Ill.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798298190790787072 |
|---|---|
| addmaterial | 6 Ill. |
| autor | Begum, S. S. Dass, N. N. |
| autorsonst | Begum, S. S. Dass, N. N. |
| book_url | http://dx.doi.org/10.1002/pol.1982.170201107 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM16340979X |
| iqvoc_descriptor_keyword | iqvoc_00000092:Materials |
| issn | 0360-6376 |
| journal_name | Journal of Polymer Science: Polymer Chemistry Edition |
| materialart | 1 |
| notes | The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1982 |
| publikationsjahr_facette | 1982 |
| publikationsjahr_intervall | 8019:1980-1984 |
| publikationsjahr_sort | 1982 |
| publikationsort | New York |
| publisher | Wiley-Blackwell |
| reference | 20 (1982), S. 3115-3120 |
| schlagwort | Physics Polymer and Materials Science |
| search_space | articles |
| shingle_author_1 | Begum, S. S. Dass, N. N. |
| shingle_author_2 | Begum, S. S. Dass, N. N. |
| shingle_author_3 | Begum, S. S. Dass, N. N. |
| shingle_author_4 | Begum, S. S. Dass, N. N. |
| shingle_catch_all_1 | Begum, S. S. Dass, N. N. Interaction of poly(vinyl acetate) radical with iron (III) complexes Physics Polymer and Materials Science Physics Polymer and Materials Science The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C. 0360-6376 03606376 Wiley-Blackwell |
| shingle_catch_all_2 | Begum, S. S. Dass, N. N. Interaction of poly(vinyl acetate) radical with iron (III) complexes Physics Polymer and Materials Science Physics Polymer and Materials Science The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C. 0360-6376 03606376 Wiley-Blackwell |
| shingle_catch_all_3 | Begum, S. S. Dass, N. N. Interaction of poly(vinyl acetate) radical with iron (III) complexes Physics Polymer and Materials Science Physics Polymer and Materials Science The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C. 0360-6376 03606376 Wiley-Blackwell |
| shingle_catch_all_4 | Begum, S. S. Dass, N. N. Interaction of poly(vinyl acetate) radical with iron (III) complexes Physics Polymer and Materials Science Physics Polymer and Materials Science The polymerization of vinyl acetate in N,N-dimethylformamide (DMF) at 60°C initiated by AIBN in the presence of [Fe(DMF)6](ClO4)3 and Fe(N3)3 had been studied. Fe(N3)3 was produced in situ by mixing solid sodium azide (NaN3) and hexakis(N,N-dimethylformamide) iron (III) perchlorate, [Fe(DMF)6](ClO4)3, in the ratio of 3:1. The velocity constant kx for the interaction of poly(vinyl acetate) radical with [Fe(DMF)6]3+ was found to be 1.44 × 103L mol-1 s-1 and that for the interaction of poly(vinyl acetate) radical with Fe(N3)3 to be 3.44 × 105 L mol-1 s-1 at 60°C. 0360-6376 03606376 Wiley-Blackwell |
| shingle_title_1 | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| shingle_title_2 | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| shingle_title_3 | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| shingle_title_4 | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:19:57.765Z |
| titel | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| titel_suche | Interaction of poly(vinyl acetate) radical with iron (III) complexes |
| topic | V |
| uid | nat_lic_papers_NLM16340979X |