Rate constants for quenching of O2(1Δg) with sulfur compounds
Raja, Nalini ; Chatha, J. P. S. ; Arora, P. K. ; Vohra, K. G.
New York, NY : Wiley-Blackwell
Published 1984
New York, NY : Wiley-Blackwell
Published 1984
| ISSN: |
0538-8066
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|---|---|
| Keywords: |
Chemistry ; Physical Chemistry
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| Source: |
Wiley InterScience Backfile Collection 1832-2000
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| Topics: |
Chemistry and Pharmacology
|
| Notes: |
The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds.
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| Additional Material: |
3 Ill.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798298197768011777 |
|---|---|
| addmaterial | 3 Ill. |
| autor | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| autorsonst | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| book_url | http://dx.doi.org/10.1002/kin.550160303 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM162456972 |
| issn | 0538-8066 |
| journal_name | International Journal of Chemical Kinetics |
| materialart | 1 |
| notes | The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1984 |
| publikationsjahr_facette | 1984 |
| publikationsjahr_intervall | 8019:1980-1984 |
| publikationsjahr_sort | 1984 |
| publikationsort | New York, NY |
| publisher | Wiley-Blackwell |
| reference | 16 (1984), S. 205-211 |
| schlagwort | Chemistry Physical Chemistry |
| search_space | articles |
| shingle_author_1 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| shingle_author_2 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| shingle_author_3 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| shingle_author_4 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. |
| shingle_catch_all_1 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. Rate constants for quenching of O2(1Δg) with sulfur compounds Chemistry Physical Chemistry Chemistry Physical Chemistry The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds. 0538-8066 05388066 Wiley-Blackwell |
| shingle_catch_all_2 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. Rate constants for quenching of O2(1Δg) with sulfur compounds Chemistry Physical Chemistry Chemistry Physical Chemistry The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds. 0538-8066 05388066 Wiley-Blackwell |
| shingle_catch_all_3 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. Rate constants for quenching of O2(1Δg) with sulfur compounds Chemistry Physical Chemistry Chemistry Physical Chemistry The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds. 0538-8066 05388066 Wiley-Blackwell |
| shingle_catch_all_4 | Raja, Nalini Chatha, J. P. S. Arora, P. K. Vohra, K. G. Rate constants for quenching of O2(1Δg) with sulfur compounds Chemistry Physical Chemistry Chemistry Physical Chemistry The rate constants for the quenching of O2(1Δg) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 ± 0.6) × 104, (1.8 ± 0.2) × 104, and (3.5 ± 0.6) × 103 L/mol · s for dimethyl sulfide, ethyl mercaptan, and thiophene, respectively. The other compounds have rate constants 〈9.9 × 102 L/mol · s. In the case of dimethyl sulfide, even when NO2 concentration is more than what is required to remove oxygen atoms completely, the rate constants are found to vary with different amounts of NO2. No correlation is found to exist between the logarithm of the rate constants and the ionization potentials of the compounds. 0538-8066 05388066 Wiley-Blackwell |
| shingle_title_1 | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| shingle_title_2 | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| shingle_title_3 | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| shingle_title_4 | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:20:04.236Z |
| titel | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| titel_suche | Rate constants for quenching of O2(1Δg) with sulfur compounds |
| topic | V |
| uid | nat_lic_papers_NLM162456972 |