Complexes of diorganotin(IV) dihalides with N, N′-dimethyl-2, 2′-bisimidazole
Leal, M P ; González, A Sánchez ; García, M E ; Casas, J S ; Sordo, J
New York, NY [u.a.] : Wiley-Blackwell
Published 1993
New York, NY [u.a.] : Wiley-Blackwell
Published 1993
| ISSN: |
0268-2605
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| Keywords: |
N, N′ -Dimethyl-2, 2′-bisimidazole ; diorganotin(IV) dihalides ; complexes ; Chemistry ; Organic Chemistry
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| Source: |
Wiley InterScience Backfile Collection 1832-2000
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| Topics: |
Chemistry and Pharmacology
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| Notes: |
Adducts of N, N′ -dimethyl-2, 2′-bisimidazole (DMBIm) with diethyl- and dibutyl-tin(IV) dihalides (Cl, Br) have been isolated and characterized. IR data for [SnR2X2(DMBIm)] compounds are in keeping with a six-coordinate tin atom with DMBIm acting as a bidentate ligand, whereas in [(SnR2X2)2(DMBIm)] the tin is five-coordinate and DMBIm acts as a bridging ligand. Measurements of conductivity in acetonitrile show the adducts to behave as non-ionogens in this solvent. NMR data show them to undergo dissociation in CDCl3.
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| Additional Material: |
3 Tab.
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| Type of Medium: |
Electronic Resource
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| URL: |