Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat
Bock, Hans ; Schödel, Holger ; Van, T. T. Han ; Dienelt, Rüdiger ; Gluth, Matthias
New York, NY : Wiley-Blackwell
Published 1998
New York, NY : Wiley-Blackwell
Published 1998
| ISSN: |
0941-1216
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|---|---|
| Keywords: |
Chemistry ; Organic Chemistry
|
| Source: |
Wiley InterScience Backfile Collection 1832-2000
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| Topics: |
Chemistry and Pharmacology
|
| Notes: |
Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations.
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| Additional Material: |
4 Ill.
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| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798297753739067392 |
|---|---|
| addmaterial | 4 Ill. |
| autor | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| autorsonst | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| book_url | http://dx.doi.org/10.1002/prac.19983400804 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM162419775 |
| issn | 0941-1216 |
| journal_name | Journal für Praktische Chemie/Chemiker-Zeitung |
| materialart | 1 |
| notes | Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1998 |
| publikationsjahr_facette | 1998 |
| publikationsjahr_intervall | 8004:1995-1999 |
| publikationsjahr_sort | 1998 |
| publikationsort | New York, NY |
| publisher | Wiley-Blackwell |
| reference | 340 (1998), S. 722-732 |
| schlagwort | Chemistry Organic Chemistry |
| search_space | articles |
| shingle_author_1 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| shingle_author_2 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| shingle_author_3 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| shingle_author_4 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias |
| shingle_catch_all_1 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat Chemistry Organic Chemistry Chemistry Organic Chemistry Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations. 0941-1216 09411216 Wiley-Blackwell |
| shingle_catch_all_2 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat Chemistry Organic Chemistry Chemistry Organic Chemistry Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations. 0941-1216 09411216 Wiley-Blackwell |
| shingle_catch_all_3 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat Chemistry Organic Chemistry Chemistry Organic Chemistry Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations. 0941-1216 09411216 Wiley-Blackwell |
| shingle_catch_all_4 | Bock, Hans Schödel, Holger Van, T. T. Han Dienelt, Rüdiger Gluth, Matthias Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat Chemistry Organic Chemistry Chemistry Organic Chemistry Interactions in Crystals. 136. Protonated Dipyridylamine Salts with Different Anions: Monomeric Tetraphenylborate as well as Bis(trifluormethylsulfonate), Dimeric Squarate and Polymeric Chloride DihydrateDi(pyrid-2-yl)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-yl(2′-pyridinium) amine cation contains an intramolecular hydrogen bridge N⊕H…N and is slightly folded. The squarate salt dimer exhibits additional bridges, N—H…O⊖ and O—H…O. The severely twisted di(2-pyridinium)amine dication is connected to its trifluormethylsulfonate counter anions by altogether three H-bridges, two N⊕H…O and one N—H…O. The chloride dihydrate crystallizes in layers of 16-membered rings, formed from three Cl anions and five water molecules. The diversity of the hydrogen-bridge dominated salt structures is discussed based on comparison with selected literature examples and on PM3 calculations. 0941-1216 09411216 Wiley-Blackwell |
| shingle_title_1 | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| shingle_title_2 | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| shingle_title_3 | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| shingle_title_4 | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:13:00.945Z |
| titel | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| titel_suche | Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat |
| topic | V |
| uid | nat_lic_papers_NLM162419775 |