The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents
| ISSN: |
1040-0397
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|---|---|
| Keywords: |
Chemistry ; Polymer and Materials Science
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| Source: |
Wiley InterScience Backfile Collection 1832-2000
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| Topics: |
Chemistry and Pharmacology
|
| Notes: |
The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation.
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| Additional Material: |
6 Ill.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798297851869003777 |
|---|---|
| addmaterial | 6 Ill. |
| autor | Mu, X. H. Kadish, K. M. |
| autorsonst | Mu, X. H. Kadish, K. M. |
| book_url | http://dx.doi.org/10.1002/elan.1140020105 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM159174201 |
| iqvoc_descriptor_keyword | iqvoc_00000092:Materials |
| issn | 1040-0397 |
| journal_name | Electroanalysis |
| materialart | 1 |
| notes | The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1990 |
| publikationsjahr_facette | 1990 |
| publikationsjahr_intervall | 8009:1990-1994 |
| publikationsjahr_sort | 1990 |
| publikationsort | Weinheim |
| publisher | Wiley-Blackwell |
| reference | 2 (1990), S. 15-20 |
| schlagwort | Chemistry Polymer and Materials Science |
| search_space | articles |
| shingle_author_1 | Mu, X. H. Kadish, K. M. |
| shingle_author_2 | Mu, X. H. Kadish, K. M. |
| shingle_author_3 | Mu, X. H. Kadish, K. M. |
| shingle_author_4 | Mu, X. H. Kadish, K. M. |
| shingle_catch_all_1 | Mu, X. H. Kadish, K. M. The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation. 1040-0397 10400397 Wiley-Blackwell |
| shingle_catch_all_2 | Mu, X. H. Kadish, K. M. The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation. 1040-0397 10400397 Wiley-Blackwell |
| shingle_catch_all_3 | Mu, X. H. Kadish, K. M. The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation. 1040-0397 10400397 Wiley-Blackwell |
| shingle_catch_all_4 | Mu, X. H. Kadish, K. M. The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science The construction and utilization of a column-shaped in situ thin-layer ESR spectroelectrochemical cell for both ambient and low temperature operation is reported. The working electrode is a columnshaped expanded platinum sheet of 9.4 × 4.0 mm that is placed in a 0.25 mm thick column-shaped, thin-layer chamber. The solution volume in the thin-layer chamber is 12 μL, and the total solution volume in the cell ranges between 1 and 3 mL. The application of this cell is demonstrated by time-resolved ESR spectra for electrooxidized porphyrins in methylene chloride solutions containing 0.3 M tetrabutylammonium perchlorate. The electrochemical behavior of this cell is also demonstrated by the oxidation of ferrocene under the same solution conditions at temperatures between 23 and -75°C. Well-defined ESR spectra are obtained in as short as 5-10 seconds without data manipulation. 1040-0397 10400397 Wiley-Blackwell |
| shingle_title_1 | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| shingle_title_2 | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| shingle_title_3 | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| shingle_title_4 | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:14:32.459Z |
| titel | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| titel_suche | The construction of a column-shaped, thin-layer ESR spectroelectrochemical cell for use at both ambient and low temperatures in nonaqueous solvents |
| topic | V |
| uid | nat_lic_papers_NLM159174201 |