Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors

Publication Date:
2018-11-29
Publisher:
Royal Society
Electronic ISSN:
2054-5703
Topics:
Natural Sciences in General
Keywords:
energy
Published by:
_version_ 1836399093908242432
autor Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
beschreibung Electrode material design is the key to the development of asymmetric supercapacitors with high electrochemical performances and stability. In this work, Al-doped NiO nanosheet arrays were synthesized using a facile hydrothermal method followed by a calcination process, and the synthesized arrays exhibited a superior pseudocapacitive performance, including a favourable specific capacitance of 2253 ± 105 F g –1 at a current density of 1 A g –1 , larger than that of an undoped NiO electrode (1538 ± 80 F g –1 ). More importantly, the arrays showed a high-rate capability (75% capacitance retention at 20 A g –1 ) and a high cycling stability (approx. 99% maintained after 5000 cycles). The above efficient capacitive performance benefits from the large electrochemically active area and enhanced conductivity of the arrays. Furthermore, an assembled asymmetric supercapacitor based on the Al-doped NiO arrays and N-doped multiwalled carbon nanotube ones delivered a high specific capacitance of 192 ± 23 F g –1 at 0.4 A g –1 with a high-energy density of 215 ± 15 Wh kg –1 and power density of 21.6 kW kg –1 . Additionally, the asymmetric device exhibited a durable cyclic stability (approx. 100% retention after 5000 cycles). This work with the proposed doping method will be beneficial to the construction of high-performance supercapacitor systems.
citation_standardnr 6362101
datenlieferant ipn_articles
feed_id 220702
feed_publisher Royal Society
feed_publisher_url http://royalsocietypublishing.org/
insertion_date 2018-11-29
journaleissn 2054-5703
publikationsjahr_anzeige 2018
publikationsjahr_facette 2018
publikationsjahr_intervall 7984:2015-2019
publikationsjahr_sort 2018
publisher Royal Society
quelle Royal Society Open Science
relation http://rsos.royalsocietypublishing.org/cgi/content/short/5/11/180842?rss=1
schlagwort energy
search_space articles
shingle_author_1 Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
shingle_author_2 Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
shingle_author_3 Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
shingle_author_4 Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
shingle_catch_all_1 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
energy
Electrode material design is the key to the development of asymmetric supercapacitors with high electrochemical performances and stability. In this work, Al-doped NiO nanosheet arrays were synthesized using a facile hydrothermal method followed by a calcination process, and the synthesized arrays exhibited a superior pseudocapacitive performance, including a favourable specific capacitance of 2253 ± 105 F g –1 at a current density of 1 A g –1 , larger than that of an undoped NiO electrode (1538 ± 80 F g –1 ). More importantly, the arrays showed a high-rate capability (75% capacitance retention at 20 A g –1 ) and a high cycling stability (approx. 99% maintained after 5000 cycles). The above efficient capacitive performance benefits from the large electrochemically active area and enhanced conductivity of the arrays. Furthermore, an assembled asymmetric supercapacitor based on the Al-doped NiO arrays and N-doped multiwalled carbon nanotube ones delivered a high specific capacitance of 192 ± 23 F g –1 at 0.4 A g –1 with a high-energy density of 215 ± 15 Wh kg –1 and power density of 21.6 kW kg –1 . Additionally, the asymmetric device exhibited a durable cyclic stability (approx. 100% retention after 5000 cycles). This work with the proposed doping method will be beneficial to the construction of high-performance supercapacitor systems.
Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
Royal Society
2054-5703
20545703
shingle_catch_all_2 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
energy
Electrode material design is the key to the development of asymmetric supercapacitors with high electrochemical performances and stability. In this work, Al-doped NiO nanosheet arrays were synthesized using a facile hydrothermal method followed by a calcination process, and the synthesized arrays exhibited a superior pseudocapacitive performance, including a favourable specific capacitance of 2253 ± 105 F g –1 at a current density of 1 A g –1 , larger than that of an undoped NiO electrode (1538 ± 80 F g –1 ). More importantly, the arrays showed a high-rate capability (75% capacitance retention at 20 A g –1 ) and a high cycling stability (approx. 99% maintained after 5000 cycles). The above efficient capacitive performance benefits from the large electrochemically active area and enhanced conductivity of the arrays. Furthermore, an assembled asymmetric supercapacitor based on the Al-doped NiO arrays and N-doped multiwalled carbon nanotube ones delivered a high specific capacitance of 192 ± 23 F g –1 at 0.4 A g –1 with a high-energy density of 215 ± 15 Wh kg –1 and power density of 21.6 kW kg –1 . Additionally, the asymmetric device exhibited a durable cyclic stability (approx. 100% retention after 5000 cycles). This work with the proposed doping method will be beneficial to the construction of high-performance supercapacitor systems.
Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
Royal Society
2054-5703
20545703
shingle_catch_all_3 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
energy
Electrode material design is the key to the development of asymmetric supercapacitors with high electrochemical performances and stability. In this work, Al-doped NiO nanosheet arrays were synthesized using a facile hydrothermal method followed by a calcination process, and the synthesized arrays exhibited a superior pseudocapacitive performance, including a favourable specific capacitance of 2253 ± 105 F g –1 at a current density of 1 A g –1 , larger than that of an undoped NiO electrode (1538 ± 80 F g –1 ). More importantly, the arrays showed a high-rate capability (75% capacitance retention at 20 A g –1 ) and a high cycling stability (approx. 99% maintained after 5000 cycles). The above efficient capacitive performance benefits from the large electrochemically active area and enhanced conductivity of the arrays. Furthermore, an assembled asymmetric supercapacitor based on the Al-doped NiO arrays and N-doped multiwalled carbon nanotube ones delivered a high specific capacitance of 192 ± 23 F g –1 at 0.4 A g –1 with a high-energy density of 215 ± 15 Wh kg –1 and power density of 21.6 kW kg –1 . Additionally, the asymmetric device exhibited a durable cyclic stability (approx. 100% retention after 5000 cycles). This work with the proposed doping method will be beneficial to the construction of high-performance supercapacitor systems.
Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
Royal Society
2054-5703
20545703
shingle_catch_all_4 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
energy
Electrode material design is the key to the development of asymmetric supercapacitors with high electrochemical performances and stability. In this work, Al-doped NiO nanosheet arrays were synthesized using a facile hydrothermal method followed by a calcination process, and the synthesized arrays exhibited a superior pseudocapacitive performance, including a favourable specific capacitance of 2253 ± 105 F g –1 at a current density of 1 A g –1 , larger than that of an undoped NiO electrode (1538 ± 80 F g –1 ). More importantly, the arrays showed a high-rate capability (75% capacitance retention at 20 A g –1 ) and a high cycling stability (approx. 99% maintained after 5000 cycles). The above efficient capacitive performance benefits from the large electrochemically active area and enhanced conductivity of the arrays. Furthermore, an assembled asymmetric supercapacitor based on the Al-doped NiO arrays and N-doped multiwalled carbon nanotube ones delivered a high specific capacitance of 192 ± 23 F g –1 at 0.4 A g –1 with a high-energy density of 215 ± 15 Wh kg –1 and power density of 21.6 kW kg –1 . Additionally, the asymmetric device exhibited a durable cyclic stability (approx. 100% retention after 5000 cycles). This work with the proposed doping method will be beneficial to the construction of high-performance supercapacitor systems.
Chen, J., Peng, X., Song, L., Zhang, L., Liu, X., Luo, J.
Royal Society
2054-5703
20545703
shingle_title_1 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
shingle_title_2 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
shingle_title_3 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
shingle_title_4 Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
timestamp 2025-06-30T23:37:30.444Z
titel Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
titel_suche Facile synthesis of Al-doped NiO nanosheet arrays for high-performance supercapacitors
topic TA-TD
uid ipn_articles_6362101