Fixation of CO2 along with bromopyridines on a silver electrode

Publication Date:
2018-08-16
Publisher:
Royal Society
Electronic ISSN:
2054-5703
Topics:
Natural Sciences in General
Keywords:
synthetic chemistry, environmental chemistry, green chemistry
Published by:
http://royalsocietypublishing.org/
_version_ 1836399029804597248
autor Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
beschreibung Resulting from the drastic increase of atmospheric CO 2 concentration day by day, global warming has become a serious environmental issue nowadays. The fixation of CO 2 to obtain desirable, economically competitive chemicals has recently received considerable attention. This work investigates the fixation of CO 2 along with three bromopyridines via a facile electrochemical method using a silver cathode to synthesize picolinic acids, which are important industrial and fine chemicals. Cyclic voltammetry is employed to investigate the cyclic voltammetric behaviour of bromopyridines. In addition, systematic study is conducted to study the relationships between the picolinic acids' yield and the electrolysis conditions and intrinsic parameters. The results show that the target picolinic acids' yields are strongly dependent on various conditions such as solvent, supporting electrolyte, current density, cathode material, charge passed, temperature and the nature of the substrates. Moreover, in the studied electrode materials such as Ag, Ni, Ti, Pt and GC, electrolysis and cyclic voltammetry show that Ag has a good electrocatalytic effect on the reduction and carboxylation of bromopyridine. This facile electrochemical route for fixation of CO 2 provides an indispensable reference for the conversion and utilization of CO 2 under mild conditions.
citation_standardnr 6320090
datenlieferant ipn_articles
feed_id 220702
feed_publisher Royal Society
feed_publisher_url http://royalsocietypublishing.org/
insertion_date 2018-08-16
journaleissn 2054-5703
publikationsjahr_anzeige 2018
publikationsjahr_facette 2018
publikationsjahr_intervall 7984:2015-2019
publikationsjahr_sort 2018
publisher Royal Society
quelle Royal Society Open Science
relation http://rsos.royalsocietypublishing.org/cgi/content/short/5/8/180897?rss=1
schlagwort synthetic chemistry, environmental chemistry, green chemistry
search_space articles
shingle_author_1 Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
shingle_author_2 Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
shingle_author_3 Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
shingle_author_4 Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
shingle_catch_all_1 Fixation of CO2 along with bromopyridines on a silver electrode
synthetic chemistry, environmental chemistry, green chemistry
Resulting from the drastic increase of atmospheric CO 2 concentration day by day, global warming has become a serious environmental issue nowadays. The fixation of CO 2 to obtain desirable, economically competitive chemicals has recently received considerable attention. This work investigates the fixation of CO 2 along with three bromopyridines via a facile electrochemical method using a silver cathode to synthesize picolinic acids, which are important industrial and fine chemicals. Cyclic voltammetry is employed to investigate the cyclic voltammetric behaviour of bromopyridines. In addition, systematic study is conducted to study the relationships between the picolinic acids' yield and the electrolysis conditions and intrinsic parameters. The results show that the target picolinic acids' yields are strongly dependent on various conditions such as solvent, supporting electrolyte, current density, cathode material, charge passed, temperature and the nature of the substrates. Moreover, in the studied electrode materials such as Ag, Ni, Ti, Pt and GC, electrolysis and cyclic voltammetry show that Ag has a good electrocatalytic effect on the reduction and carboxylation of bromopyridine. This facile electrochemical route for fixation of CO 2 provides an indispensable reference for the conversion and utilization of CO 2 under mild conditions.
Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
Royal Society
2054-5703
20545703
shingle_catch_all_2 Fixation of CO2 along with bromopyridines on a silver electrode
synthetic chemistry, environmental chemistry, green chemistry
Resulting from the drastic increase of atmospheric CO 2 concentration day by day, global warming has become a serious environmental issue nowadays. The fixation of CO 2 to obtain desirable, economically competitive chemicals has recently received considerable attention. This work investigates the fixation of CO 2 along with three bromopyridines via a facile electrochemical method using a silver cathode to synthesize picolinic acids, which are important industrial and fine chemicals. Cyclic voltammetry is employed to investigate the cyclic voltammetric behaviour of bromopyridines. In addition, systematic study is conducted to study the relationships between the picolinic acids' yield and the electrolysis conditions and intrinsic parameters. The results show that the target picolinic acids' yields are strongly dependent on various conditions such as solvent, supporting electrolyte, current density, cathode material, charge passed, temperature and the nature of the substrates. Moreover, in the studied electrode materials such as Ag, Ni, Ti, Pt and GC, electrolysis and cyclic voltammetry show that Ag has a good electrocatalytic effect on the reduction and carboxylation of bromopyridine. This facile electrochemical route for fixation of CO 2 provides an indispensable reference for the conversion and utilization of CO 2 under mild conditions.
Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
Royal Society
2054-5703
20545703
shingle_catch_all_3 Fixation of CO2 along with bromopyridines on a silver electrode
synthetic chemistry, environmental chemistry, green chemistry
Resulting from the drastic increase of atmospheric CO 2 concentration day by day, global warming has become a serious environmental issue nowadays. The fixation of CO 2 to obtain desirable, economically competitive chemicals has recently received considerable attention. This work investigates the fixation of CO 2 along with three bromopyridines via a facile electrochemical method using a silver cathode to synthesize picolinic acids, which are important industrial and fine chemicals. Cyclic voltammetry is employed to investigate the cyclic voltammetric behaviour of bromopyridines. In addition, systematic study is conducted to study the relationships between the picolinic acids' yield and the electrolysis conditions and intrinsic parameters. The results show that the target picolinic acids' yields are strongly dependent on various conditions such as solvent, supporting electrolyte, current density, cathode material, charge passed, temperature and the nature of the substrates. Moreover, in the studied electrode materials such as Ag, Ni, Ti, Pt and GC, electrolysis and cyclic voltammetry show that Ag has a good electrocatalytic effect on the reduction and carboxylation of bromopyridine. This facile electrochemical route for fixation of CO 2 provides an indispensable reference for the conversion and utilization of CO 2 under mild conditions.
Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
Royal Society
2054-5703
20545703
shingle_catch_all_4 Fixation of CO2 along with bromopyridines on a silver electrode
synthetic chemistry, environmental chemistry, green chemistry
Resulting from the drastic increase of atmospheric CO 2 concentration day by day, global warming has become a serious environmental issue nowadays. The fixation of CO 2 to obtain desirable, economically competitive chemicals has recently received considerable attention. This work investigates the fixation of CO 2 along with three bromopyridines via a facile electrochemical method using a silver cathode to synthesize picolinic acids, which are important industrial and fine chemicals. Cyclic voltammetry is employed to investigate the cyclic voltammetric behaviour of bromopyridines. In addition, systematic study is conducted to study the relationships between the picolinic acids' yield and the electrolysis conditions and intrinsic parameters. The results show that the target picolinic acids' yields are strongly dependent on various conditions such as solvent, supporting electrolyte, current density, cathode material, charge passed, temperature and the nature of the substrates. Moreover, in the studied electrode materials such as Ag, Ni, Ti, Pt and GC, electrolysis and cyclic voltammetry show that Ag has a good electrocatalytic effect on the reduction and carboxylation of bromopyridine. This facile electrochemical route for fixation of CO 2 provides an indispensable reference for the conversion and utilization of CO 2 under mild conditions.
Zhang, Y., Yu, S., Luo, P., Xu, S., Zhang, X., Zhou, H., Du, J., Yang, J., Xin, N., Kong, Y., Liu, J., Chen, B., Lu, J.
Royal Society
2054-5703
20545703
shingle_title_1 Fixation of CO2 along with bromopyridines on a silver electrode
shingle_title_2 Fixation of CO2 along with bromopyridines on a silver electrode
shingle_title_3 Fixation of CO2 along with bromopyridines on a silver electrode
shingle_title_4 Fixation of CO2 along with bromopyridines on a silver electrode
timestamp 2025-06-30T23:36:29.108Z
titel Fixation of CO2 along with bromopyridines on a silver electrode
titel_suche Fixation of CO2 along with bromopyridines on a silver electrode
topic TA-TD
uid ipn_articles_6320090