Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts

Publication Date:
2018-07-02
Publisher:
MDPI Publishing
Electronic ISSN:
1996-1073
Topics:
Energy, Environment Protection, Nuclear Power Engineering
Published by:
http://www.mdpi.com/
_version_ 1836398995181666304
autor Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
beschreibung Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Baltazar de Castro Martyn Pillinger Luís Cunha-Silva Salete S. Balula This work proposes an efficient desulfurization system to produce low sulfur diesel under sustainable and moderate experimental conditions. Treatment of a real diesel with a sulfur content of 2300 ppm led to 80% desulfurization after 2 h. The processes used conciliate liquid-liquid extraction and sulfur oxidative catalysis. The catalytic performance of the commercial Keggin-polyoxomolybdate H3[PMo12O40] (PMo12) was strategically increased by simple cation exchange, using a long carbon chain (ODAPMo12, ODA = CH3(CH2)17(CH3)3N), and by its incorporation into the Metal-Organic Framework (MOF) NH2-MIL-101(Cr), forming a new active heterogeneous PMo12@MOF composite catalyst. Activity of both catalysts was similar; however, the solid catalyst could be easily recovered and reused, and its stability was confirmed after multiple continuous cycles.
citation_standardnr 6296747
datenlieferant ipn_articles
feed_id 109050
feed_publisher MDPI Publishing
feed_publisher_url http://www.mdpi.com/
insertion_date 2018-07-02
journaleissn 1996-1073
publikationsjahr_anzeige 2018
publikationsjahr_facette 2018
publikationsjahr_intervall 7984:2015-2019
publikationsjahr_sort 2018
publisher MDPI Publishing
quelle Energies
relation http://www.mdpi.com/1996-1073/11/7/1696
search_space articles
shingle_author_1 Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
shingle_author_2 Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
shingle_author_3 Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
shingle_author_4 Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
shingle_catch_all_1 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Baltazar de Castro Martyn Pillinger Luís Cunha-Silva Salete S. Balula This work proposes an efficient desulfurization system to produce low sulfur diesel under sustainable and moderate experimental conditions. Treatment of a real diesel with a sulfur content of 2300 ppm led to 80% desulfurization after 2 h. The processes used conciliate liquid-liquid extraction and sulfur oxidative catalysis. The catalytic performance of the commercial Keggin-polyoxomolybdate H3[PMo12O40] (PMo12) was strategically increased by simple cation exchange, using a long carbon chain (ODAPMo12, ODA = CH3(CH2)17(CH3)3N), and by its incorporation into the Metal-Organic Framework (MOF) NH2-MIL-101(Cr), forming a new active heterogeneous PMo12@MOF composite catalyst. Activity of both catalysts was similar; however, the solid catalyst could be easily recovered and reused, and its stability was confirmed after multiple continuous cycles.
Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
MDPI Publishing
1996-1073
19961073
shingle_catch_all_2 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Baltazar de Castro Martyn Pillinger Luís Cunha-Silva Salete S. Balula This work proposes an efficient desulfurization system to produce low sulfur diesel under sustainable and moderate experimental conditions. Treatment of a real diesel with a sulfur content of 2300 ppm led to 80% desulfurization after 2 h. The processes used conciliate liquid-liquid extraction and sulfur oxidative catalysis. The catalytic performance of the commercial Keggin-polyoxomolybdate H3[PMo12O40] (PMo12) was strategically increased by simple cation exchange, using a long carbon chain (ODAPMo12, ODA = CH3(CH2)17(CH3)3N), and by its incorporation into the Metal-Organic Framework (MOF) NH2-MIL-101(Cr), forming a new active heterogeneous PMo12@MOF composite catalyst. Activity of both catalysts was similar; however, the solid catalyst could be easily recovered and reused, and its stability was confirmed after multiple continuous cycles.
Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
MDPI Publishing
1996-1073
19961073
shingle_catch_all_3 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Baltazar de Castro Martyn Pillinger Luís Cunha-Silva Salete S. Balula This work proposes an efficient desulfurization system to produce low sulfur diesel under sustainable and moderate experimental conditions. Treatment of a real diesel with a sulfur content of 2300 ppm led to 80% desulfurization after 2 h. The processes used conciliate liquid-liquid extraction and sulfur oxidative catalysis. The catalytic performance of the commercial Keggin-polyoxomolybdate H3[PMo12O40] (PMo12) was strategically increased by simple cation exchange, using a long carbon chain (ODAPMo12, ODA = CH3(CH2)17(CH3)3N), and by its incorporation into the Metal-Organic Framework (MOF) NH2-MIL-101(Cr), forming a new active heterogeneous PMo12@MOF composite catalyst. Activity of both catalysts was similar; however, the solid catalyst could be easily recovered and reused, and its stability was confirmed after multiple continuous cycles.
Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
MDPI Publishing
1996-1073
19961073
shingle_catch_all_4 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Baltazar de Castro Martyn Pillinger Luís Cunha-Silva Salete S. Balula This work proposes an efficient desulfurization system to produce low sulfur diesel under sustainable and moderate experimental conditions. Treatment of a real diesel with a sulfur content of 2300 ppm led to 80% desulfurization after 2 h. The processes used conciliate liquid-liquid extraction and sulfur oxidative catalysis. The catalytic performance of the commercial Keggin-polyoxomolybdate H3[PMo12O40] (PMo12) was strategically increased by simple cation exchange, using a long carbon chain (ODAPMo12, ODA = CH3(CH2)17(CH3)3N), and by its incorporation into the Metal-Organic Framework (MOF) NH2-MIL-101(Cr), forming a new active heterogeneous PMo12@MOF composite catalyst. Activity of both catalysts was similar; however, the solid catalyst could be easily recovered and reused, and its stability was confirmed after multiple continuous cycles.
Carlos M. Granadeiro; Pedro M. C. Ferreira; Diana Julião; Luís A. Ribeiro; Rita Valença; Jorge C. Ribeiro; Isabel S. Gonçalves; Baltazar de Castro; Martyn Pillinger; Luís Cunha-Silva; Salete S. Balula
MDPI Publishing
1996-1073
19961073
shingle_title_1 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
shingle_title_2 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
shingle_title_3 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
shingle_title_4 Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
timestamp 2025-06-30T23:35:56.016Z
titel Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
titel_suche Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts
topic ZP
uid ipn_articles_6296747