Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule
Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y.
American Association for the Advancement of Science (AAAS)
Published 2018
American Association for the Advancement of Science (AAAS)
Published 2018
| Publication Date: |
2018-05-04
|
|---|---|
| Publisher: |
American Association for the Advancement of Science (AAAS)
|
| Print ISSN: |
0036-8075
|
| Electronic ISSN: |
1095-9203
|
| Topics: |
Biology
Chemistry and Pharmacology
Geosciences
Computer Science
Medicine
Natural Sciences in General
Physics
|
| Keywords: |
Chemistry
|
| Published by: |
| _version_ | 1836398918608355328 |
|---|---|
| autor | Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. |
| beschreibung | Plasmon-induced chemical reactions of molecules adsorbed on metal nanostructures are attracting increased attention for photocatalytic reactions. However, the mechanism remains controversial because of the difficulty of direct observation of the chemical reactions in the plasmonic field, which is strongly localized near the metal surface. We used a scanning tunneling microscope (STM) to achieve real-space and real-time observation of a plasmon-induced chemical reaction at the single-molecule level. A single dimethyl disulfide molecule on silver and copper surfaces was dissociated by the optically excited plasmon at the STM junction. The STM study combined with theoretical calculations shows that this plasmon-induced chemical reaction occurred by a direct intramolecular excitation mechanism. |
| citation_standardnr | 6251051 |
| datenlieferant | ipn_articles |
| feed_id | 25 |
| feed_publisher | American Association for the Advancement of Science (AAAS) |
| feed_publisher_url | http://www.aaas.org/ |
| insertion_date | 2018-05-04 |
| journaleissn | 1095-9203 |
| journalissn | 0036-8075 |
| publikationsjahr_anzeige | 2018 |
| publikationsjahr_facette | 2018 |
| publikationsjahr_intervall | 7984:2015-2019 |
| publikationsjahr_sort | 2018 |
| publisher | American Association for the Advancement of Science (AAAS) |
| quelle | Science |
| relation | http://science.sciencemag.org/cgi/content/short/360/6388/521?rss=1 |
| schlagwort | Chemistry |
| search_space | articles |
| shingle_author_1 | Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. |
| shingle_author_2 | Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. |
| shingle_author_3 | Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. |
| shingle_author_4 | Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. |
| shingle_catch_all_1 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule Chemistry Plasmon-induced chemical reactions of molecules adsorbed on metal nanostructures are attracting increased attention for photocatalytic reactions. However, the mechanism remains controversial because of the difficulty of direct observation of the chemical reactions in the plasmonic field, which is strongly localized near the metal surface. We used a scanning tunneling microscope (STM) to achieve real-space and real-time observation of a plasmon-induced chemical reaction at the single-molecule level. A single dimethyl disulfide molecule on silver and copper surfaces was dissociated by the optically excited plasmon at the STM junction. The STM study combined with theoretical calculations shows that this plasmon-induced chemical reaction occurred by a direct intramolecular excitation mechanism. Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. American Association for the Advancement of Science (AAAS) 0036-8075 00368075 1095-9203 10959203 |
| shingle_catch_all_2 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule Chemistry Plasmon-induced chemical reactions of molecules adsorbed on metal nanostructures are attracting increased attention for photocatalytic reactions. However, the mechanism remains controversial because of the difficulty of direct observation of the chemical reactions in the plasmonic field, which is strongly localized near the metal surface. We used a scanning tunneling microscope (STM) to achieve real-space and real-time observation of a plasmon-induced chemical reaction at the single-molecule level. A single dimethyl disulfide molecule on silver and copper surfaces was dissociated by the optically excited plasmon at the STM junction. The STM study combined with theoretical calculations shows that this plasmon-induced chemical reaction occurred by a direct intramolecular excitation mechanism. Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. American Association for the Advancement of Science (AAAS) 0036-8075 00368075 1095-9203 10959203 |
| shingle_catch_all_3 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule Chemistry Plasmon-induced chemical reactions of molecules adsorbed on metal nanostructures are attracting increased attention for photocatalytic reactions. However, the mechanism remains controversial because of the difficulty of direct observation of the chemical reactions in the plasmonic field, which is strongly localized near the metal surface. We used a scanning tunneling microscope (STM) to achieve real-space and real-time observation of a plasmon-induced chemical reaction at the single-molecule level. A single dimethyl disulfide molecule on silver and copper surfaces was dissociated by the optically excited plasmon at the STM junction. The STM study combined with theoretical calculations shows that this plasmon-induced chemical reaction occurred by a direct intramolecular excitation mechanism. Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. American Association for the Advancement of Science (AAAS) 0036-8075 00368075 1095-9203 10959203 |
| shingle_catch_all_4 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule Chemistry Plasmon-induced chemical reactions of molecules adsorbed on metal nanostructures are attracting increased attention for photocatalytic reactions. However, the mechanism remains controversial because of the difficulty of direct observation of the chemical reactions in the plasmonic field, which is strongly localized near the metal surface. We used a scanning tunneling microscope (STM) to achieve real-space and real-time observation of a plasmon-induced chemical reaction at the single-molecule level. A single dimethyl disulfide molecule on silver and copper surfaces was dissociated by the optically excited plasmon at the STM junction. The STM study combined with theoretical calculations shows that this plasmon-induced chemical reaction occurred by a direct intramolecular excitation mechanism. Kazuma, E., Jung, J., Ueba, H., Trenary, M., Kim, Y. American Association for the Advancement of Science (AAAS) 0036-8075 00368075 1095-9203 10959203 |
| shingle_title_1 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| shingle_title_2 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| shingle_title_3 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| shingle_title_4 | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| timestamp | 2025-06-30T23:34:42.834Z |
| titel | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| titel_suche | Real-space and real-time observation of a plasmon-induced chemical reaction of a single molecule |
| topic | W V TE-TZ SQ-SU WW-YZ TA-TD U |
| uid | ipn_articles_6251051 |