Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst
| Publication Date: |
2018-02-07
|
|---|---|
| Publisher: |
Wiley-Blackwell
|
| Print ISSN: |
0930-7516
|
| Electronic ISSN: |
1521-4125
|
| Topics: |
Chemistry and Pharmacology
Process Engineering, Biotechnology, Nutrition Technology
|
| Published by: |
| _version_ | 1836398780734242816 |
|---|---|
| autor | Abhimanyu K. Yadav, Prakash D. Vaidya |
| beschreibung | Bio-oil is a candidate renewable feedstock for hydrogen (H 2 ) production. In this work, n -butanol was chosen as a model compound representing alcohols in the bio-oil aqueous fraction. H 2 production from steam reforming of n -butanol was investigated in a fixed-bed reactor using commercial Ni/hydrotalcite catalyst. A plausible reaction pathway in presence of Ni was discussed. The rise in reforming temperature, space time and steam/carbon ratio in feed enhanced n -butanol conversion and H 2 yield. Reaction kinetics was studied in the chemical control regime (623-773 K). The reaction order with respect to n -butanol (one) and the activation energy (50 kJ/mol) were found. |
| citation_standardnr | 6157122 |
| datenlieferant | ipn_articles |
| feed_id | 4519 |
| feed_publisher | Wiley-Blackwell |
| feed_publisher_url | http://www.wiley.com/wiley-blackwell |
| insertion_date | 2018-02-07 |
| journaleissn | 1521-4125 |
| journalissn | 0930-7516 |
| publikationsjahr_anzeige | 2018 |
| publikationsjahr_facette | 2018 |
| publikationsjahr_intervall | 7984:2015-2019 |
| publikationsjahr_sort | 2018 |
| publisher | Wiley-Blackwell |
| quelle | Chemical Engineering and Technology |
| relation | http://onlinelibrary.wiley.com/resolve/doi?DOI=10.1002%2Fceat.201600738 |
| search_space | articles |
| shingle_author_1 | Abhimanyu K. Yadav, Prakash D. Vaidya |
| shingle_author_2 | Abhimanyu K. Yadav, Prakash D. Vaidya |
| shingle_author_3 | Abhimanyu K. Yadav, Prakash D. Vaidya |
| shingle_author_4 | Abhimanyu K. Yadav, Prakash D. Vaidya |
| shingle_catch_all_1 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst Bio-oil is a candidate renewable feedstock for hydrogen (H 2 ) production. In this work, n -butanol was chosen as a model compound representing alcohols in the bio-oil aqueous fraction. H 2 production from steam reforming of n -butanol was investigated in a fixed-bed reactor using commercial Ni/hydrotalcite catalyst. A plausible reaction pathway in presence of Ni was discussed. The rise in reforming temperature, space time and steam/carbon ratio in feed enhanced n -butanol conversion and H 2 yield. Reaction kinetics was studied in the chemical control regime (623-773 K). The reaction order with respect to n -butanol (one) and the activation energy (50 kJ/mol) were found. Abhimanyu K. Yadav, Prakash D. Vaidya Wiley-Blackwell 0930-7516 09307516 1521-4125 15214125 |
| shingle_catch_all_2 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst Bio-oil is a candidate renewable feedstock for hydrogen (H 2 ) production. In this work, n -butanol was chosen as a model compound representing alcohols in the bio-oil aqueous fraction. H 2 production from steam reforming of n -butanol was investigated in a fixed-bed reactor using commercial Ni/hydrotalcite catalyst. A plausible reaction pathway in presence of Ni was discussed. The rise in reforming temperature, space time and steam/carbon ratio in feed enhanced n -butanol conversion and H 2 yield. Reaction kinetics was studied in the chemical control regime (623-773 K). The reaction order with respect to n -butanol (one) and the activation energy (50 kJ/mol) were found. Abhimanyu K. Yadav, Prakash D. Vaidya Wiley-Blackwell 0930-7516 09307516 1521-4125 15214125 |
| shingle_catch_all_3 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst Bio-oil is a candidate renewable feedstock for hydrogen (H 2 ) production. In this work, n -butanol was chosen as a model compound representing alcohols in the bio-oil aqueous fraction. H 2 production from steam reforming of n -butanol was investigated in a fixed-bed reactor using commercial Ni/hydrotalcite catalyst. A plausible reaction pathway in presence of Ni was discussed. The rise in reforming temperature, space time and steam/carbon ratio in feed enhanced n -butanol conversion and H 2 yield. Reaction kinetics was studied in the chemical control regime (623-773 K). The reaction order with respect to n -butanol (one) and the activation energy (50 kJ/mol) were found. Abhimanyu K. Yadav, Prakash D. Vaidya Wiley-Blackwell 0930-7516 09307516 1521-4125 15214125 |
| shingle_catch_all_4 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst Bio-oil is a candidate renewable feedstock for hydrogen (H 2 ) production. In this work, n -butanol was chosen as a model compound representing alcohols in the bio-oil aqueous fraction. H 2 production from steam reforming of n -butanol was investigated in a fixed-bed reactor using commercial Ni/hydrotalcite catalyst. A plausible reaction pathway in presence of Ni was discussed. The rise in reforming temperature, space time and steam/carbon ratio in feed enhanced n -butanol conversion and H 2 yield. Reaction kinetics was studied in the chemical control regime (623-773 K). The reaction order with respect to n -butanol (one) and the activation energy (50 kJ/mol) were found. Abhimanyu K. Yadav, Prakash D. Vaidya Wiley-Blackwell 0930-7516 09307516 1521-4125 15214125 |
| shingle_title_1 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| shingle_title_2 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| shingle_title_3 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| shingle_title_4 | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| timestamp | 2025-06-30T23:32:31.464Z |
| titel | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| titel_suche | Reaction kinetics of steam reforming of n-butanol over Ni/hydrotalcite catalyst |
| topic | V ZM |
| uid | ipn_articles_6157122 |