Search Results - (Author, Cooperation:J. Waldmann)
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1H. Teeling ; B. M. Fuchs ; D. Becher ; C. Klockow ; A. Gardebrecht ; C. M. Bennke ; M. Kassabgy ; S. Huang ; A. J. Mann ; J. Waldmann ; M. Weber ; A. Klindworth ; A. Otto ; J. Lange ; J. Bernhardt ; C. Reinsch ; M. Hecker ; J. Peplies ; F. D. Bockelmann ; U. Callies ; G. Gerdts ; A. Wichels ; K. H. Wiltshire ; F. O. Glockner ; T. Schweder ; R. Amann
American Association for the Advancement of Science (AAAS)
Published 2012Staff ViewPublication Date: 2012-05-05Publisher: American Association for the Advancement of Science (AAAS)Print ISSN: 0036-8075Electronic ISSN: 1095-9203Topics: BiologyChemistry and PharmacologyComputer ScienceMedicineNatural Sciences in GeneralPhysicsKeywords: Alphaproteobacteria/enzymology/genetics/*growth & development/metabolism ; Bacterial Proteins/genetics/metabolism ; Bacteroidetes/enzymology/genetics/*growth & development/metabolism ; Diatoms/*growth & development/metabolism ; *Ecosystem ; *Eutrophication ; Gammaproteobacteria/enzymology/genetics/*growth & development/metabolism ; Glycoside Hydrolases/genetics/metabolism ; Membrane Proteins/genetics/metabolism ; Membrane Transport Proteins/genetics/metabolism ; Metagenome ; Microbial Interactions ; North Sea ; Phosphates/metabolism ; Phytoplankton/*growth & development/metabolism ; Seawater/*microbiology ; Sulfatases/genetics/metabolismPublished by: -
2Staff View
ISSN: 0005-2744Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002Topics: BiologyType of Medium: Electronic ResourceURL: -
3Staff View
ISSN: 0301-0104Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002Topics: Chemistry and PharmacologyPhysicsType of Medium: Electronic ResourceURL: -
4Staff View
ISSN: 0022-2313Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002Topics: Chemistry and PharmacologyPhysicsType of Medium: Electronic ResourceURL: -
5Staff View
ISSN: 0301-0104Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002Topics: Chemistry and PharmacologyPhysicsType of Medium: Electronic ResourceURL: -
6Kruck, Th. ; Waldmann, J. ; Höfler, M. ; Birkenhäger, G. ; Odenbrett, Ch.
Weinheim : Wiley-Blackwell
Published 1973Staff ViewISSN: 0044-2313Keywords: Chemistry ; Inorganic ChemistrySource: Wiley InterScience Backfile Collection 1832-2000Topics: Chemistry and PharmacologyDescription / Table of Contents: Fluorine Exchange in Trifltiorophosphinemetal Complexes. IVThe Reaction of Nitrosyltrifluorophosphirie Complexes of Iron and Cobalt with Alkoxid- and Hydroxid-IonsFe(NO)2(PF3)2, 1, and Co(NO)(PF3)3, 2, react with alcoxids and phenoxid by a complete F/OR-exchange to the corresponding phosphite complexes Fe(NO)2P(OR)3)2 and Co(NO)(P(OR)3)3, (R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, C6H5), 3-13. The nitrosyltrifluorophosphine complexes 1 and 2 change only one or two fluorine atoms against OH--ions to give difluorophosphito complexes: The reaction of 1 with a diisopropylamine/water mixture yields the bis(difluorophosphito) complex [Fe(NO)2(PF2O)2]2-, 15, with 2 under identical conditions [Co(NO)(PF3)2 PF2O]-, 14, is obtained; 1 and 2 react with Ba(OH)2 in THF to give [Fe(NO)2(PF3)PF2O]- resp. 14, the latter reacts under harder conditions partially to [Co(NO)(PF3)(PF2O)2]2-. These difluorophosphito complexes, which are isolated as salts with the cations [(i-C3H7)2NH2]+ and Ba2+, can be alkylated to the corresponding difluorethoxyphosphine derivates of 1 and 2, Fe(NO)2 (PF3)2-n(PF2OC2H5)n (n = 1,2) and Co(NO)(PF3)2PF2OC2H5. All compounds are characterised by IR and mass spectra.Notes: Fe(NO)2(PF3)2, 1, und Co(NO)(PF3)3, 2, tauschen bei der Umsetzung mit Alkoholaten und Phenolat sämtliche Fluoratome gegen RO-Gruppen aus unter Bildung der entsprechenden Phosphitkomplexe Fe(NO)2(P(OR)3)2 bzw. Co(NO)(P(OR)3)3 (R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, C6H5), 3-13. Beide Nitrosyl-trifluorphosphin-Komplexe gehen maximal nur einen zweifachen F/OH-Austausch zu Difluorphosphito-Komplexen ein: In einem Diisopropylamin/Wasser-Gemisch liefert 1 den Bis(difluorphosphito)-Komplex[Fe(NO)2(PF2O)2] 2-, 15, 2 unter gleichen Bedingungen [Co(NO)(PF3)2PF2O- 14; die Umsetzung von 1 und 2 mit Ba(OH)2 in Tetrahydrofuran führt zu [Fe(NO)2(PF3) PF2O]- bzw. 14, welches sich unter drastischen Bedingungen teilweise zu [Co(NO)(PF3) (PF2O)2]2- umsetzt. Diese Difluorphosphito-Komplexe, die als Salze mit den Kationen [(i-C3H7)2NH2]+ bzw. Ba2+ anfallen, können zu den entsprechenden Difluoräthoxy-Derivaten von 1 und 2, Fe(NO)2 (PF3)2-n(PF2OC2H5)n (n = 1, 2) bzw. Co(NO)(PF3)2PF2OC2H5, alkyliert werden. Sämtliche Verbindungen werden anhand der IR- und Massenspektren charakterisiert.Additional Material: 8 Tab.Type of Medium: Electronic ResourceURL: