Search Results - (Author, Cooperation:B. Whittington)
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1C. E. Conn ; R. Bythell-Douglas ; D. Neumann ; S. Yoshida ; B. Whittington ; J. H. Westwood ; K. Shirasu ; C. S. Bond ; K. A. Dyer ; D. C. Nelson
American Association for the Advancement of Science (AAAS)
Published 2015Staff ViewPublication Date: 2015-08-01Publisher: American Association for the Advancement of Science (AAAS)Print ISSN: 0036-8075Electronic ISSN: 1095-9203Topics: BiologyChemistry and PharmacologyComputer ScienceMedicineNatural Sciences in GeneralPhysicsKeywords: Arabidopsis/*metabolism/*parasitology ; Arabidopsis Proteins/*classification/genetics/metabolism ; *Biological Evolution ; Gene Dosage ; Germination ; Heterocyclic Compounds, 1-Ring/*metabolism ; Host-Parasite Interactions ; Hydrolases/*classification/genetics/metabolism ; Lactones/*metabolism ; Orobanchaceae/*enzymology/genetics/growth & development ; Phylogeny ; Plant Growth Regulators/*metabolism ; Plant Roots/metabolism/parasitology ; Plants, Genetically Modified/genetics/metabolismPublished by: -
2Staff View
ISSN: 1572-879XKeywords: Ion exchange ; AlPO4-5 ; VAPO-5 ; defect sites ; copper ; ESRSource: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyNotes: Abstract The reaction of copper salts with AlPO4-5 or Vv-VAPO-5 under acidic (CuCl2, pH adjusted to 2) but especially basic conditions (Cu(NH3) 4 2+ , pH adjusted to 9) gives ion incorporations greater than expected by a simple ion exchange mechanism (both AlPO4-5 and Vv-VAPO-5 could be expected to have no cation exchange capacity). Ion incorporation is proposed to occur initially at defect sites, and examination of the ESR spectrum of a dehydrated, evacuated CuCl2-exchanged AlPO4-5 shows that these defect sites give rise to a number of unique environments upon CuII incorporation. The CuCl2-exchanged VAPO-5 retains a significant toluene accessibility to the Vv sites in the VAPO-5. However, the toluene accessibility in the Cu(NH3) 4 2+ -exchanged VAPO-5 is significantly reduced and we propose this is due to a combination of the presence of crystalline CuO and structural collapse from reaction with base (NH4OH). The ability of treatment with base (NH4OH, pH ≈ 13) to restrict access of toluene to the Vv sites of the original VAPO-5 was verified in a separate experiment.Type of Medium: Electronic ResourceURL: