Search Results - (Author, Cooperation:A. V. Neimark)
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1H. Sung Cho ; H. Deng ; K. Miyasaka ; Z. Dong ; M. Cho ; A. V. Neimark ; J. Ku Kang ; O. M. Yaghi ; O. Terasaki
Nature Publishing Group (NPG)
Published 2015Staff ViewPublication Date: 2015-11-10Publisher: Nature Publishing Group (NPG)Print ISSN: 0028-0836Electronic ISSN: 1476-4687Topics: BiologyChemistry and PharmacologyMedicineNatural Sciences in GeneralPhysicsPublished by: -
2Staff View
ISSN: 1573-9171Keywords: adsorption ; adsorption volume ; compressibility ; activated carbon ; benzeneSource: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyNotes: Abstract Compressibility of the adsorbate has been taken into account in calculating the maximum adsorption in micropores. On this basis, an equation has been derived for improvement of the theory of three-dimensional filling of micropores in application to the calculation of micropore volume by the Dubinin-Radushkevich equation. Evaluations for the case of benzene adsorption on activated carbons at ∼20°C have shown that the accounting for adsorbate compressibility leads to corrections of the Dubinin-Radushkevich theory amounting to approximately 10%.Type of Medium: Electronic ResourceURL: -
3Hanson, M. ; Eray, B. ; Unger, K. ; Neimark, A. V. ; Schmid, J. ; Albert, K. ; Bayer, E.
Springer
Published 1993Staff ViewISSN: 1612-1112Keywords: Column liquid chromatography ; Reversed phase packings ; Polybutadiene coating ; Polymer coatingsSource: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyNotes: Summary Non-wetting viscous liquids such as oligobutadiene prefer “active” sites such as pores during the process of physisorption. Thus, polybutadiene (PBD) coatings on porous silica do not result in a homogeneous polymer film but in an inhomogeneous loading where the bulk polymer is mainly sited in the pores of the silica. An increasing polymer loading leads to increasingly filled pores instead of a thicker polymer film. We cannot exclude the possibility that most of the surface is covered at least with a thin polymer film since the chromatographic behaviour is relatively good for polypeptides, which are highly susceptible to the silanol groups of silica.Type of Medium: Electronic ResourceURL: -
4Staff View
ISSN: 1573-8779Source: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyType of Medium: Electronic ResourceURL: -
5Staff View
ISSN: 1588-2837Source: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyDescription / Table of Contents: Abstract На основе представлений о механизме переноса влаги в испаряющейся капиллярно-пористой частице проведен анализ распределения осажденного активного компонента. Предложены формулы для доли грубодисперсной фазы в зависимости от параметра осаждения. Расчеты, проведенные с использованием статической модели пористой среды, находятся в удовлетворительном согласии с экспериментальными данными.Notes: Abstract The distribution of the precipitated active component has been analyzed using the concepts of moisture transfer mechanism for the evaporation of porous materials. Formulas are proposed for the low-dispersity phase, depending on the precipitation parameter. The calculations performed using a statistical porous environment model are in reasonable agreement with the experimental data.Type of Medium: Electronic ResourceURL: -
6Hein, Nguyen Thi Minh ; Serpinskii, V. V. ; Neimark, A. V. ; Moskovskaya, T. A.
Springer
Published 1986Staff ViewISSN: 1573-9171Source: Springer Online Journal Archives 1860-2000Topics: Chemistry and PharmacologyNotes: Conclusions 1. Pore volume distributions were obtained as a function of radius using the Kelvin method, the Dubinin method, and percolation theory, for MSK silica gel. 2. The t-curve for n-pentane adsorbed on silica gel was obtained. 3. The position of the maximum in the distribution curve calculated using a model based upon percolation theory is virtually identical with the result obtained using the Dubinin method. Percolation theory produces a substantially larger contribution from pores having the largest radii to the total pore volume.Type of Medium: Electronic ResourceURL: